Total synthesis of (+)-allocyathin B2, (-)-erinacine B, and (-)-erinacine E

Hideaki Watanabe, Masashi Takano, Masahisa Nakada

    Research output: Contribution to journalArticle

    10 Citations (Scopus)

    Abstract

    This article describes the enantioselective total synthesis of (+)-allocyathin B2 and (-)-erinacine B via the convergent approach using new chiral building blocks prepared by the asymmetric catalysis developed in our research, and also describes the biomimetic total synthesis of (-)-erinacine E. The convergent approach developed in these studies would enable the divergent synthesis of optically pure cyathane diterpenoids and their derivatives for SAR.

    Original languageEnglish
    Pages (from-to)1116-1125
    Number of pages10
    JournalYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
    Volume66
    Issue number11
    Publication statusPublished - 2008 Nov

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    ASJC Scopus subject areas

    • Organic Chemistry

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