Total Synthesis of (‒)-Grayanotoxin III

Toshiyuki Kan, Seijiro Hosokawa, Shinji Nara, Masato Oikawa, Shinya Ito, Fuyuhiko Matsuda, Haruhisa Shirahama

Research output: Contribution to journalLetter

89 Citations (Scopus)

Abstract

Total synthesis of (‒)-grayanotoxin III (3), a unique tetracyclic diterpene isolated from the leaves of various plants of the family Ericaceae, has been successfully accomplished featuring the highly stereoselective cyclization reactions induced by SmI2.

Original languageEnglish
Pages (from-to)5532-5534
Number of pages3
JournalJournal of Organic Chemistry
Volume59
Issue number19
DOIs
Publication statusPublished - 1994 Sep 1
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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  • Cite this

    Kan, T., Hosokawa, S., Nara, S., Oikawa, M., Ito, S., Matsuda, F., & Shirahama, H. (1994). Total Synthesis of (‒)-Grayanotoxin III. Journal of Organic Chemistry, 59(19), 5532-5534. https://doi.org/10.1021/jo00098a009