Total synthesis of (-)-grayanotoxin III

Toshiyuki Kan, Seijiro Hosokawa, Shinji Nara, Masato Oikawa, Shinya Ito, Fuyuhiko Matsuda, Haruhisa Shirahama

Research output: Contribution to journalArticle

85 Citations (Scopus)

Abstract

Total synthesis of (-)-grayanotoxin III (3), a unique tetracyclic diterpene isolated from the leaves of various plants of the family Ericaceae, has been successfully accomplished featuring the highly stereoselective cyclization reactions induced by SmI2.

Original languageEnglish
Pages (from-to)5532-5534
Number of pages3
JournalJournal of Organic Chemistry
Volume59
Issue number19
Publication statusPublished - 1994
Externally publishedYes

Fingerprint

Diterpenes
Cyclization
grayanotoxin III

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Kan, T., Hosokawa, S., Nara, S., Oikawa, M., Ito, S., Matsuda, F., & Shirahama, H. (1994). Total synthesis of (-)-grayanotoxin III. Journal of Organic Chemistry, 59(19), 5532-5534.

Total synthesis of (-)-grayanotoxin III. / Kan, Toshiyuki; Hosokawa, Seijiro; Nara, Shinji; Oikawa, Masato; Ito, Shinya; Matsuda, Fuyuhiko; Shirahama, Haruhisa.

In: Journal of Organic Chemistry, Vol. 59, No. 19, 1994, p. 5532-5534.

Research output: Contribution to journalArticle

Kan, T, Hosokawa, S, Nara, S, Oikawa, M, Ito, S, Matsuda, F & Shirahama, H 1994, 'Total synthesis of (-)-grayanotoxin III', Journal of Organic Chemistry, vol. 59, no. 19, pp. 5532-5534.
Kan T, Hosokawa S, Nara S, Oikawa M, Ito S, Matsuda F et al. Total synthesis of (-)-grayanotoxin III. Journal of Organic Chemistry. 1994;59(19):5532-5534.
Kan, Toshiyuki ; Hosokawa, Seijiro ; Nara, Shinji ; Oikawa, Masato ; Ito, Shinya ; Matsuda, Fuyuhiko ; Shirahama, Haruhisa. / Total synthesis of (-)-grayanotoxin III. In: Journal of Organic Chemistry. 1994 ; Vol. 59, No. 19. pp. 5532-5534.
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