Transfer printing of self-folding polymer-metal bilayer particles

Al De Leon, Andrew C. Barnes, Patrick Thomas, Johnathan ODonnell, Christian A. Zorman, Rigoberto C. Advincula

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A simple and robust alternative for fabricating stimuli-responsive 2D self-folding films was introduced. The approach combines metal-sputtering, layer-by-layer assembly of polyelectrolytes, and transfer-printing of the bilayer film onto a substrate coated with a sacrificial layer. With this technique, self-folding bilayer films can be fabricated without using harsh chemical etchants, complicated chemical synthesis, or complex lithographic techniques. Upon release, the microsized 2D film is shown to reconfigure into a 3D structure caused by a mismatch in the properties of the individual layers. The actuation of the bilayer film can be triggered by partial swelling due to absorption of water or by partial expansion of one of the layers due to an increase in temperature.

Original languageEnglish
Pages (from-to)22695-22700
Number of pages6
JournalACS Applied Materials and Interfaces
Volume6
Issue number24
DOIs
Publication statusPublished - 2014 Dec 24
Externally publishedYes

Keywords

  • FT-IR imaging
  • microcontact printing
  • polymer-metal bilayer
  • self-folding
  • stimuli-responsive
  • transfer printing

ASJC Scopus subject areas

  • Materials Science(all)

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  • Cite this

    De Leon, A., Barnes, A. C., Thomas, P., ODonnell, J., Zorman, C. A., & Advincula, R. C. (2014). Transfer printing of self-folding polymer-metal bilayer particles. ACS Applied Materials and Interfaces, 6(24), 22695-22700. https://doi.org/10.1021/am5068172