Tree initiation characteristics of epoxy resin and epoxy/clay nanocomoposite

Stephanie Raetzke, Yoshimichi Ohki, Takahiro Imai, Toshikatsu Tanaka, Josef Kindersberger

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

Tree initiation behavior of an epoxy nanocomposite with 5 wt % nanoclay (layered silicate) was investigated for ac voltage in comparison to neat epoxy resin without fillers. To shorten the time for experiments, 600 Hz was used instead of 60 Hz, as acceleration for tree initiation had been confirmed at 10 kVrms and 14 kVrms between the two frequencies. V-t characteristics for tree initiation rather than tree growth to bridge the electrodes were obtained for conventional type of treeing specimens with an embedded steel needle subjected to voltages from 2 kVrms to 14 kVrms. As a result, it was clarified that tree initiation V-t characteristics were improved by approximately one order of magnitude for the epoxy/nanoclay composite compared to the neat epoxy resin. Initial formation of trees is generally considered to be directly related to the fatigue of matter stressed by electric ac fields at comparatively low field strength. Experimentally obtained prolongation of tree initiation time especially at low electric field can be ascribed to the suppression of such a fatigue through an interaction of injected electrons with nanoscale filler particles or interfaces between nanoscale filler particles and their surrounding polymer matrices. Mechanisms for improvement of time to tree initiation are discussed on the basis of the above concept including a multicore model that some of the authors have proposed.

Original languageEnglish
Article number5293962
Pages (from-to)1473-1480
Number of pages8
JournalIEEE Transactions on Dielectrics and Electrical Insulation
Volume16
Issue number5
DOIs
Publication statusPublished - 2009 Oct

Keywords

  • (insulation)
  • Epoxy resin
  • Multi-core model
  • Nanodielectrics
  • Polymer nanocomposite
  • Trees

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

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