Trimethylsilylation of biotite

Kazuyuki kuroda, Chuzo Kato

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Organic solvent soluble organosilicate compounds retaining silicate backbone were obtained by the reaction between biotite and trimethylsilylating reagent. The soluble product which was formed at room temperature or at reflux temperature was a viscous liquid and was soluble in a wide range of organic solvents, but insoluble in water. Molecular weights of the soluble products and their thin-layer chromatograms made it clear that the soluble products consisted of several trimethylsilylated derivatives of silicic acids which were mainly the derivatives of mono- and disilicic acid. The influence of reaction temperature for the trimethylsilylation reaction also was discussed.

Original languageEnglish
Pages (from-to)407-410
Number of pages4
JournalClays and Clay Minerals
Volume25
Issue number6
DOIs
Publication statusPublished - 1977 Dec

ASJC Scopus subject areas

  • Water Science and Technology
  • Soil Science
  • Geochemistry and Petrology
  • Earth and Planetary Sciences (miscellaneous)

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