Abstract
Organic solvent soluble organosilicate compounds retaining silicate backbone were obtained by the reaction between biotite and trimethylsilylating reagent. The soluble product which was formed at room temperature or at reflux temperature was a viscous liquid and was soluble in a wide range of organic solvents, but insoluble in water. Molecular weights of the soluble products and their thin-layer chromatograms made it clear that the soluble products consisted of several trimethylsilylated derivatives of silicic acids which were mainly the derivatives of mono- and disilicic acid. The influence of reaction temperature for the trimethylsilylation reaction also was discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 407-410 |
| Number of pages | 4 |
| Journal | Clays and Clay Minerals |
| Volume | 25 |
| Issue number | 6 |
| Publication status | Published - 1977 Dec |
Fingerprint
ASJC Scopus subject areas
- Water Science and Technology
- Geochemistry and Petrology
- Earth and Planetary Sciences (miscellaneous)
- Soil Science
Cite this
Trimethylsilylation of biotite. / Kuroda, Kazuyuki; Kato, Chuzo.
In: Clays and Clay Minerals, Vol. 25, No. 6, 12.1977, p. 407-410.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Trimethylsilylation of biotite
AU - Kuroda, Kazuyuki
AU - Kato, Chuzo
PY - 1977/12
Y1 - 1977/12
N2 - Organic solvent soluble organosilicate compounds retaining silicate backbone were obtained by the reaction between biotite and trimethylsilylating reagent. The soluble product which was formed at room temperature or at reflux temperature was a viscous liquid and was soluble in a wide range of organic solvents, but insoluble in water. Molecular weights of the soluble products and their thin-layer chromatograms made it clear that the soluble products consisted of several trimethylsilylated derivatives of silicic acids which were mainly the derivatives of mono- and disilicic acid. The influence of reaction temperature for the trimethylsilylation reaction also was discussed.
AB - Organic solvent soluble organosilicate compounds retaining silicate backbone were obtained by the reaction between biotite and trimethylsilylating reagent. The soluble product which was formed at room temperature or at reflux temperature was a viscous liquid and was soluble in a wide range of organic solvents, but insoluble in water. Molecular weights of the soluble products and their thin-layer chromatograms made it clear that the soluble products consisted of several trimethylsilylated derivatives of silicic acids which were mainly the derivatives of mono- and disilicic acid. The influence of reaction temperature for the trimethylsilylation reaction also was discussed.
UR - http://www.scopus.com/inward/record.url?scp=19144362503&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=19144362503&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:19144362503
VL - 25
SP - 407
EP - 410
JO - Clays and Clay Minerals
JF - Clays and Clay Minerals
SN - 0009-8604
IS - 6
ER -