Trimethylsilylation of biotite

Kazuyuki kuroda; Chuzo Kato

doi:10.1346/CCMN.1977.0250605

Trimethylsilylation of biotite

Kazuyuki kuroda, Chuzo Kato

School of Advanced Science and Engineering

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

Organic solvent soluble organosilicate compounds retaining silicate backbone were obtained by the reaction between biotite and trimethylsilylating reagent. The soluble product which was formed at room temperature or at reflux temperature was a viscous liquid and was soluble in a wide range of organic solvents, but insoluble in water. Molecular weights of the soluble products and their thin-layer chromatograms made it clear that the soluble products consisted of several trimethylsilylated derivatives of silicic acids which were mainly the derivatives of mono- and disilicic acid. The influence of reaction temperature for the trimethylsilylation reaction also was discussed.

Original language	English
Pages (from-to)	407-410
Number of pages	4
Journal	Clays and Clay Minerals
Volume	25
Issue number	6
DOIs	https://doi.org/10.1346/CCMN.1977.0250605
Publication status	Published - 1977 Dec

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ASJC Scopus subject areas

Water Science and Technology
Soil Science
Geochemistry and Petrology
Earth and Planetary Sciences (miscellaneous)

Cite this

kuroda, K., & Kato, C. (1977). Trimethylsilylation of biotite. Clays and Clay Minerals, 25(6), 407-410. https://doi.org/10.1346/CCMN.1977.0250605

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10.1346/CCMN.1977.0250605