Two-dimensional penning ionization electron spectroscopy of dichlorobenzenes: Orbital reactivity and anisotropic interaction of dichlorobenzenes with He*(23S)

Kohei Imura, Naoki Kishimoto, Koichi Ohno

Research output: Contribution to journalArticle

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Abstract

Ionization of dichlorobenzenes with metastable He*(23S) atoms was studied by two-dimensional (collision-energy/electron-energy-resolved) Penning ionization electron spectroscopy. Collision energy dependence of the partial ionization cross sections (CEDPICS), which reflects the interaction potential energy between the molecule and He*(23S), showed anisotropic interaction around the molecules. The π and n (nonbonding) orbitals regions of the molecules showed attractive interactions. It was also found that the magnitude of attractive interaction around the Cl atom lone pair region perpendicular to the phenyl ring was o- > p- > m-C6H4Cl2. Negative slopes of CEDPICS for σ type bands indicate an attractive effect for ionization reaction by a substitution of the Cl atom.

Original languageEnglish
Pages (from-to)9111-9122
Number of pages12
JournalJournal of Physical Chemistry A
Volume105
Issue number40
DOIs
Publication statusPublished - 2001 Oct 11
Externally publishedYes

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Electron spectroscopy
Ionization
electron spectroscopy
reactivity
ionization
orbitals
ionization cross sections
collisions
Atoms
Molecules
interactions
atoms
molecules
energy
Potential energy
potential energy
electron energy
substitutes
slopes
Substitution reactions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Two-dimensional penning ionization electron spectroscopy of dichlorobenzenes : Orbital reactivity and anisotropic interaction of dichlorobenzenes with He*(23S). / Imura, Kohei; Kishimoto, Naoki; Ohno, Koichi.

In: Journal of Physical Chemistry A, Vol. 105, No. 40, 11.10.2001, p. 9111-9122.

Research output: Contribution to journalArticle

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