@article{271e077fafa14cc69246f7aedc1e7010,
title = "Two-step synthesis of a red-emissive warped nanographene derivative: Via a ten-fold C-H borylation",
abstract = "The regioselective ten-fold borylation of warped nanographene (WNG: C80H30) was achieved by modifying the reaction conditions of a previously reported Ir-catalyzed C-H borylation, affording decaborylated WNG in high yield (75%) from pristine WNG. The solid-state structure of decaborylated WNG was confirmed by X-ray crystallography. Corresponding decaarylated WNGs containing electron-withdrawing and -donating groups were synthesized from decaborylated WNG using Suzuki-Miyaura cross-coupling reactions to afford the red-emissive warped nanographene derivative.",
author = "Kenta Kato and Lin, {Hsing An} and Motonobu Kuwayama and Mai Nagase and Yasutomo Segawa and Scott, {Lawrence T.} and Kenichiro Itami",
note = "Funding Information: This work was supported by the ERATO program from JST (JPMJER1302 to K. I.), the Funding Program for KAKENHI from MEXT (JP19H05463 to K. I. and JP16K05771 and JP19H02701 to Y. S.), a Grant-in-Aid for Scientic Research on Innovative Areas “p-Figuration” from JSPS (JP17H05149 to Y. S.), the Noguchi Institute (to Y. S.) and the US National Science Foundation (CHE-1149096 to L. T. S.). K. K. acknowledges the IGER Program in Green Natural Sciences, Nagoya University and the JSPS fellowship for young scientists. Calculations were performed using the resources of the Research Center for Computational Science, Okazaki, Japan. ITbM is supported by the World Premier International Research Center Initiative (WPI), Japan. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2019.",
year = "2019",
doi = "10.1039/c9sc03061a",
language = "English",
volume = "10",
pages = "9038--9041",
journal = "Chemical Science",
issn = "2041-6520",
publisher = "Royal Society of Chemistry",
number = "39",
}