Ultrathin film self-assembly of hybrid organic-inorganic metal coordination polymers

Houston Byrd, Charles E. Holloway, Jessica Pogue, Sandy Kircus, Rigoberto C. Advincula, Wolfgang Knoll

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

We have investigated the self-assembly of ultrathin zirconium coordination monomer and polymer films using a layer-by-layer approach. These materials are of great interest for incorporating metal ion (inorganic) moieties in organic (polymer) films with applications ranging from conductors to catalytic materials. The differences between the polymer and monomer assembly from solution are described. These differences were investigated using UV-vis spectroscopy, AFM, and surface plasmon spectroscopy. The differences in orientation, morphology, roughness, and linearity of deposition reflect the conformational limitations of the polymer toward self-assembly. On the other hand, the sequential assembly of the monomer and Zr metal ion indicates the strong coordination between the metal and the organic ligands, resulting in robust homogeneous films.

Original languageEnglish
Pages (from-to)10322-10328
Number of pages7
JournalLangmuir
Volume16
Issue number26
DOIs
Publication statusPublished - 2000 Dec 26
Externally publishedYes

Fingerprint

Ultrathin films
coordination polymers
Self assembly
self assembly
Polymers
Monomers
Metals
Polymer films
monomers
polymers
metals
Organic polymers
assembly
Ultraviolet spectroscopy
Zirconium
Surface roughness
Ligands
Spectroscopy
spectroscopy
linearity

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Cite this

Byrd, H., Holloway, C. E., Pogue, J., Kircus, S., Advincula, R. C., & Knoll, W. (2000). Ultrathin film self-assembly of hybrid organic-inorganic metal coordination polymers. Langmuir, 16(26), 10322-10328. https://doi.org/10.1021/la001049l

Ultrathin film self-assembly of hybrid organic-inorganic metal coordination polymers. / Byrd, Houston; Holloway, Charles E.; Pogue, Jessica; Kircus, Sandy; Advincula, Rigoberto C.; Knoll, Wolfgang.

In: Langmuir, Vol. 16, No. 26, 26.12.2000, p. 10322-10328.

Research output: Contribution to journalArticle

Byrd, H, Holloway, CE, Pogue, J, Kircus, S, Advincula, RC & Knoll, W 2000, 'Ultrathin film self-assembly of hybrid organic-inorganic metal coordination polymers', Langmuir, vol. 16, no. 26, pp. 10322-10328. https://doi.org/10.1021/la001049l
Byrd H, Holloway CE, Pogue J, Kircus S, Advincula RC, Knoll W. Ultrathin film self-assembly of hybrid organic-inorganic metal coordination polymers. Langmuir. 2000 Dec 26;16(26):10322-10328. https://doi.org/10.1021/la001049l
Byrd, Houston ; Holloway, Charles E. ; Pogue, Jessica ; Kircus, Sandy ; Advincula, Rigoberto C. ; Knoll, Wolfgang. / Ultrathin film self-assembly of hybrid organic-inorganic metal coordination polymers. In: Langmuir. 2000 ; Vol. 16, No. 26. pp. 10322-10328.
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