Ultrathin film self-assembly of hybrid organic-inorganic metal coordination polymers as investigated by surface plasmon spectroscopy

Charles E. Holloway, Houston Byrd, Rigoberto C. Advincula, Wolfgang Knoll

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A series of zirconium coordination polymers was investigated. The surface plasmon resonance spectroscopy (SPS) method was utilized primarily to investigate the self-assembly, adsorption properties, and film homogeneity of these layers. The surface plasmon resonance curve is determined by measuring the reflected intensity as a function of incident angle and resonance corresponding to a minimum in the measured reflectivity. Analysis of the curve displacement yields the optical thickness of the adsorbed film. Unique determination of the geometric thickness is not possible, but relies upon an assumed value for the film refractive index.

Original languageEnglish
Pages (from-to)613-614
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume41
Issue number1
Publication statusPublished - 2000 Mar
Externally publishedYes

Fingerprint

Ultrathin films
Self assembly
Polymers
Metals
Surface plasmon resonance
Spectroscopy
Zirconium
Refractive index
Adsorption

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Ultrathin film self-assembly of hybrid organic-inorganic metal coordination polymers as investigated by surface plasmon spectroscopy. / Holloway, Charles E.; Byrd, Houston; Advincula, Rigoberto C.; Knoll, Wolfgang.

In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 41, No. 1, 03.2000, p. 613-614.

Research output: Contribution to journalArticle

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