UNDERPOTENTIAL DEPOSITION OF LITHIUM ON SINGLE CRYSTAL METAL SURFACE IN APROTIC MEDIA.

R. McIntyre, Daniel Alberto Scherson, D. M. Kolb, H. Gerischer

Research output: Contribution to journalConference article

1 Citation (Scopus)

Abstract

This communication will examines certain aspects of Li underpotential deposition (UPD) on single crystal Au(111), Ag(111) and Cu(111) in three different aprotic solvents, dimethylformamide (DMF), acetronitride (ACN) and propylene carbonate(PC). Figs. show examples of the UPD process observed for Ki on the above substrates in PC. The solid curves show the UPD process and the broken curves show the bulk process. These results together with similar results obtained in ACN and DMF are discussed with particular emphasis on the kinetic and thermodynamic aspects governing the reversibility of the UPD process for these systems.

Original languageEnglish
Pages (from-to)184-185
Number of pages2
JournalElectrochemical Society Extended Abstracts
Volume84-1
Publication statusPublished - 1984 Dec 1
Externally publishedYes

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Lithium
Single crystals
Dimethylformamide
Metals
Propylene
Carbonates
Thermodynamics
Kinetics
Communication
Substrates

ASJC Scopus subject areas

  • Engineering(all)

Cite this

UNDERPOTENTIAL DEPOSITION OF LITHIUM ON SINGLE CRYSTAL METAL SURFACE IN APROTIC MEDIA. / McIntyre, R.; Scherson, Daniel Alberto; Kolb, D. M.; Gerischer, H.

In: Electrochemical Society Extended Abstracts, Vol. 84-1, 01.12.1984, p. 184-185.

Research output: Contribution to journalConference article

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