Unexpected large spectral shift from blue to green region in a light-emitting electrochemical cells

Henk J. Bolink, Eugenio Coronado, Rubén D. Costa, Nora Lardiés, Md K. Nazeeruddin, Enrique Ortí

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A new, but archetype compound [Ir(ppy-F2)2Me 4phen]PF6, where ppy-F2 is 2-(2′, 4′-fluorophenyl)pyridine and Me4phen is 3,4,7,8-tetraraethyl-1, 10-phenanthroline, was synthesized and used to prepare a solid-state light-emitting electrochemical cell (LEC). This complex emits blue light with a maximum at 476 nm when photoexcited in a thin film, with a photoluminescence quantum yield of 52 %. It yields an efficient single-component solid-state electroluminescence device with a current efficiency reaching 5.5 cd/A and a maximum power efficiency of 5.8 Lm/Watt. However, the electroluminiscence spectrum is shifted with respect to the photoluminiscence spectrum by 80 nm resulting in the emission of green light. We demonstrate that this unexpected shift in emission spectrum is not originating from the way of excitation, nor from the presence of large concentrations of ions, but is related to the concentration of the ionic transition metal complex in the thin film. The origin of the concentration dependent emission is extensively commented and argued to be related to the population of either 3LC π-π* or 3MLCT triplet states, in diluted and concentrated films, respectively. Using quantum chemical calculations we demonstrate that three low-energy triplet states are present with only 0.1 eV difference in energy and that their associated emission wavelengths differ by as much as 60 nm from each other.

Original languageEnglish
Title of host publicationOrganic Optoelectronics and Photonics III
DOIs
Publication statusPublished - 2008
Externally publishedYes
EventOrganic Optoelectronics and Photonics III - Strasbourg, France
Duration: 2008 Apr 72008 Apr 10

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume6999
ISSN (Print)0277-786X

Conference

ConferenceOrganic Optoelectronics and Photonics III
CountryFrance
CityStrasbourg
Period08/4/708/4/10

Keywords

  • Blue emission
  • Electroluminescence
  • Iridium emitters
  • Light-emitting electrochemical cells (LECs)
  • Organometallic complexes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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  • Cite this

    Bolink, H. J., Coronado, E., Costa, R. D., Lardiés, N., Nazeeruddin, M. K., & Ortí, E. (2008). Unexpected large spectral shift from blue to green region in a light-emitting electrochemical cells. In Organic Optoelectronics and Photonics III [69992L] (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 6999). https://doi.org/10.1117/12.781825