Unveiling Three-Dimensional Stacking Sequences of 1T Phase MoS2 Monolayers by Electron Diffraction

Ziqian Wang, Shoucong Ning, Takeshi Fujita, Akihiko Hirata, Mingwei Chen

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The phase transition between semiconducting 1H to metallic 1T phases in monolayered transition metal dichalcogenides (TMDs) essentially involves three-dimensional (3D) structure changes of asymmetric relocations of S atoms at the top and bottom of the one-unit-cell crystals. Even though the phase transition has a profound influence on properties and applications of 2D TMDs, a viable approach to experimentally characterize the stacking sequences of the vertically asymmetrical 1T phase is still not available. Here, we report an electron diffraction method based on dynamic electron scattering to characterize the stacking sequences of 1T MoS2 monolayers. This study provides an approach to unveil the 3D structure of 2D crystals and to explore the underlying mechanisms of semiconductor-to-metal transition of monolayer TMDs.

Original languageEnglish
Pages (from-to)10308-10316
Number of pages9
JournalACS Nano
Volume10
Issue number11
DOIs
Publication statusPublished - 2016 Nov 22

Keywords

  • MoS
  • electron diffraction
  • phase interface
  • transition metal dichalcogenide
  • two-dimensional materials

ASJC Scopus subject areas

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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