Vapor phase polymerization of pyrrole and thiophene using iron(III) sulfonates as oxidizing agents

Bjorn Winther Jensen, Jun Chen, Keld West, Gordon Wallace

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146 Citations (Scopus)

Abstract

Vapor phase polymerization is a versatile technique that can be used to obtain highly conducting coatings of conjugated polymer on both conducting and nonconducting substrates. This is demonstrated here by preparation of polypyrrole, polybithiopene, and polyterthiopene, coatings that otherwise must be prepared electrochemically in order to achieve the desired high conjugation. The method is based on the use of organic ferric sulfonates as oxidant as these salts easily form smooth, noncrystalline films. By proper choice of the sulfonate anion, the oxidizing power of the ferric salt can be varied over a wide range. The described technique can easily be adapted to different patterning techniques.

Original languageEnglish
Pages (from-to)5930-5935
Number of pages6
JournalMacromolecules
Volume37
Issue number16
DOIs
Publication statusPublished - 2004 Aug 10
Externally publishedYes

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ASJC Scopus subject areas

  • Materials Chemistry

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