Very slow formation of copper sulfide and cobalt sulfide nanoparticles in montmorillonite

Nithima Khaorapapong; Areeporn Ontam; Makoto Ogawa

doi:10.1016/j.clay.2010.10.030

Very slow formation of copper sulfide and cobalt sulfide nanoparticles in montmorillonite

Nithima Khaorapapong^*, Areeporn Ontam, Makoto Ogawa

^*Corresponding author for this work

Waseda University

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Intercalation of semiconductor nanoparticles, copper sulfide or cobalt sulfide, into montmorillonite was carried out by solid-solid reactions of Cu(II)- or Co(II)-montmorillonite with sodium sulfide at room temperature. The intercalation compounds were characterized by X-ray diffraction, thermal analysis, transmission electron microscopy, Raman, UV-visible and photoluminescence spectroscopy. The photoluminescent copper sulfide and cobalt sulfide nanoparticles in the interlayer spaces formed after the sample storage at room temperature for several months.

Original language	English
Pages (from-to)	182-186
Number of pages	5
Journal	Applied Clay Science
Volume	51
Issue number	1-2
DOIs	https://doi.org/10.1016/j.clay.2010.10.030
Publication status	Published - 2011 Jan

Keywords

Cobalt sulfide
Copper sulfide
Intercalation
Montmorillonite
Solid-solid reactions

ASJC Scopus subject areas

Geochemistry and Petrology
Geology

Access to Document

10.1016/j.clay.2010.10.030

Cite this

@article{e528fa551bf74ae59556ab768de688b7,

title = "Very slow formation of copper sulfide and cobalt sulfide nanoparticles in montmorillonite",

abstract = "Intercalation of semiconductor nanoparticles, copper sulfide or cobalt sulfide, into montmorillonite was carried out by solid-solid reactions of Cu(II)- or Co(II)-montmorillonite with sodium sulfide at room temperature. The intercalation compounds were characterized by X-ray diffraction, thermal analysis, transmission electron microscopy, Raman, UV-visible and photoluminescence spectroscopy. The photoluminescent copper sulfide and cobalt sulfide nanoparticles in the interlayer spaces formed after the sample storage at room temperature for several months.",

keywords = "Cobalt sulfide, Copper sulfide, Intercalation, Montmorillonite, Solid-solid reactions",

author = "Nithima Khaorapapong and Areeporn Ontam and Makoto Ogawa",

year = "2011",

month = jan,

doi = "10.1016/j.clay.2010.10.030",

language = "English",

volume = "51",

pages = "182--186",

journal = "Applied Clay Science",

issn = "0169-1317",

publisher = "Elsevier BV",

number = "1-2",

}

TY - JOUR

T1 - Very slow formation of copper sulfide and cobalt sulfide nanoparticles in montmorillonite

AU - Khaorapapong, Nithima

AU - Ontam, Areeporn

AU - Ogawa, Makoto

PY - 2011/1

Y1 - 2011/1

N2 - Intercalation of semiconductor nanoparticles, copper sulfide or cobalt sulfide, into montmorillonite was carried out by solid-solid reactions of Cu(II)- or Co(II)-montmorillonite with sodium sulfide at room temperature. The intercalation compounds were characterized by X-ray diffraction, thermal analysis, transmission electron microscopy, Raman, UV-visible and photoluminescence spectroscopy. The photoluminescent copper sulfide and cobalt sulfide nanoparticles in the interlayer spaces formed after the sample storage at room temperature for several months.

AB - Intercalation of semiconductor nanoparticles, copper sulfide or cobalt sulfide, into montmorillonite was carried out by solid-solid reactions of Cu(II)- or Co(II)-montmorillonite with sodium sulfide at room temperature. The intercalation compounds were characterized by X-ray diffraction, thermal analysis, transmission electron microscopy, Raman, UV-visible and photoluminescence spectroscopy. The photoluminescent copper sulfide and cobalt sulfide nanoparticles in the interlayer spaces formed after the sample storage at room temperature for several months.

KW - Cobalt sulfide

KW - Copper sulfide

KW - Intercalation

KW - Montmorillonite

KW - Solid-solid reactions

UR - http://www.scopus.com/inward/record.url?scp=78650736473&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78650736473&partnerID=8YFLogxK

U2 - 10.1016/j.clay.2010.10.030

DO - 10.1016/j.clay.2010.10.030

M3 - Article

AN - SCOPUS:78650736473

SN - 0169-1317

VL - 51

SP - 182

EP - 186

JO - Applied Clay Science

JF - Applied Clay Science

IS - 1-2

ER -

Very slow formation of copper sulfide and cobalt sulfide nanoparticles in montmorillonite

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this