"visible" 5d Orbital States in a Pleochroic Oxychloride

Daigorou Hirai, Takeshi Yajima, Daisuke Nishio-Hamane, Changsu Kim, Hidefumi Akiyama, Mitsuaki Kawamura, Takahiro Misawa, Nobuyuki Abe, Taka Hisa Arima, Zenji Hiroi

Research output: Contribution to journalArticle

4 Citations (Scopus)


Transition metal compounds sometimes exhibit attractive colors. Here, we report a new oxychloride, Ca3ReO5Cl2, that shows unusually distinct pleochroism; that is, the material exhibits different colors depending on the viewing direction. This pleochroism is a consequence of the coincidental complex crystal field splitting of the 5d orbitals of the Re6+ ion in a square-pyramidal coordination of low symmetry in the energy range of the visible spectrum. Since the relevant d-d transitions show characteristic polarization dependence according to the optical selection rule, the orbital states are "visible" in Ca3ReO5Cl2.

Original languageEnglish
Pages (from-to)10784-10789
Number of pages6
JournalJournal of the American Chemical Society
Issue number31
Publication statusPublished - 2017 Aug 9
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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    Hirai, D., Yajima, T., Nishio-Hamane, D., Kim, C., Akiyama, H., Kawamura, M., Misawa, T., Abe, N., Arima, T. H., & Hiroi, Z. (2017). "visible" 5d Orbital States in a Pleochroic Oxychloride. Journal of the American Chemical Society, 139(31), 10784-10789. https://doi.org/10.1021/jacs.7b05128