Visible-light active thin-film WO3 photocatalyst with controlled high-rate deposition by low-damage reactive-gas-flow sputtering

Nobuto Oka, Akiyo Murata, Shin Ichi Nakamura, Junjun Jia, Yoshinori Iwabuchi, Hidefumi Kotsubo, Yuzo Shigesato

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

A process based on reactive gas flow sputtering (GFS) for depositing visible-light active photocatalytic WO3 films at high deposition rates and with high film quality was successfully demonstrated. The deposition rate for this process was over 10 times higher than that achieved by the conventional sputtering process and the process was highly stable. Furthermore, Pt nanoparticle-loaded WO3 films deposited by the GFS process exhibited much higher photocatalytic activity than those deposited by conventional sputtering, where the photocatalytic activity was evaluated by the extent of decomposition of CH3CHO under visible light irradiation. The decomposition time for 60 ppm of CH3CHO was 7.5 times more rapid on the films deposited by the GFS process than on the films deposited by the conventional process. During GFS deposition, there are no high-energy particles bombarding the growing film surface, whereas the bombardment of the surface with high-energy particles is a key feature of conventional sputtering. Hence, the WO3 films deposited by GFS should be of higher quality, with fewer structural defects, which would lead to a decrease in the number of centers for electron-hole recombination and to the efficient use of photogenerated holes for the decomposition of CH3CHO.

Original languageEnglish
Article number104407
JournalAPL Materials
Volume3
Issue number10
DOIs
Publication statusPublished - 2015 Oct 1
Externally publishedYes

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Photocatalysts
Deposition rates
Sputtering
Flow of gases
Thin films
Decomposition
Film growth
Irradiation
Nanoparticles
Defects
Electrons

ASJC Scopus subject areas

  • Materials Science(all)
  • Engineering(all)

Cite this

Oka, N., Murata, A., Nakamura, S. I., Jia, J., Iwabuchi, Y., Kotsubo, H., & Shigesato, Y. (2015). Visible-light active thin-film WO3 photocatalyst with controlled high-rate deposition by low-damage reactive-gas-flow sputtering. APL Materials, 3(10), [104407]. https://doi.org/10.1063/1.4922942

Visible-light active thin-film WO3 photocatalyst with controlled high-rate deposition by low-damage reactive-gas-flow sputtering. / Oka, Nobuto; Murata, Akiyo; Nakamura, Shin Ichi; Jia, Junjun; Iwabuchi, Yoshinori; Kotsubo, Hidefumi; Shigesato, Yuzo.

In: APL Materials, Vol. 3, No. 10, 104407, 01.10.2015.

Research output: Contribution to journalArticle

Oka, N, Murata, A, Nakamura, SI, Jia, J, Iwabuchi, Y, Kotsubo, H & Shigesato, Y 2015, 'Visible-light active thin-film WO3 photocatalyst with controlled high-rate deposition by low-damage reactive-gas-flow sputtering', APL Materials, vol. 3, no. 10, 104407. https://doi.org/10.1063/1.4922942
Oka, Nobuto ; Murata, Akiyo ; Nakamura, Shin Ichi ; Jia, Junjun ; Iwabuchi, Yoshinori ; Kotsubo, Hidefumi ; Shigesato, Yuzo. / Visible-light active thin-film WO3 photocatalyst with controlled high-rate deposition by low-damage reactive-gas-flow sputtering. In: APL Materials. 2015 ; Vol. 3, No. 10.
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