Water-triggered modulus changes of cellulose nanofiber nanocomposites with hydrophobic polymer matrices

Koffi L. Dagnon, Kadhiravan Shanmuganathan, Christoph Weder, Stuart J. Rowan

Research output: Contribution to journalArticle

98 Citations (Scopus)

Abstract

Biomimetic, stimuli-responsive nanocomposites were made using either poly(styrene-co-butadiene) (SBR) or polybutadiene (PBD) as the hydrophobic, low-modulus matrix and hydrophilic cellulose whiskers isolated from tunicates (TW) as the high-modulus filler. These materials were prepared using a template approach, which involves the formation of a percolating TW network and filling this template with either of the matrix polymers. Dynamic mechanical analysis (DMA) studies of the dry nanocomposite films reveal that the incorporation of TWs into the rubbery polymers increases the tensile storage modulus E′ significantly. The reinforcement is attributed to the formation of a three-dimensional TW network within the SBR and PBD matrices. The incorporation of the TWs did not affect the main relaxation temperature of the matrix SBR polymer, suggesting weak nanofiller-polymer interactions. Thus, the reinforcement is primarily on account of the nanofiller-nanofiller interactions, which involve hydrogen bonding. Interestingly, submersion of these hydrophobic matrix nanocomposites in water results in dramatic softening, consistent with disengagement of the TW network as a consequence of competitive hydrogen bonding with water. The kinetics of the modulus change and the amount of water uptake were shown to depend on the TW content. Given the hydrophobic nature of the matrices, it is proposed that the TWs create a percolating network of hydrophilic channels within the hydrophobic SBR and PBD matrices.

Original languageEnglish
Pages (from-to)4707-4715
Number of pages9
JournalMacromolecules
Volume45
Issue number11
DOIs
Publication statusPublished - 2012 Jun 12
Externally publishedYes

Fingerprint

Polybutadienes
Nanofibers
Polymer matrix
Cellulose
Nanocomposites
Water
Hydrogen bonds
Reinforcement
Polymers
Styrene
Nanocomposite films
Biomimetics
Dynamic mechanical analysis
Butadiene
Fillers
Elastic moduli
Kinetics
polybutadiene
Temperature

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

Cite this

Water-triggered modulus changes of cellulose nanofiber nanocomposites with hydrophobic polymer matrices. / Dagnon, Koffi L.; Shanmuganathan, Kadhiravan; Weder, Christoph; Rowan, Stuart J.

In: Macromolecules, Vol. 45, No. 11, 12.06.2012, p. 4707-4715.

Research output: Contribution to journalArticle

Dagnon, Koffi L. ; Shanmuganathan, Kadhiravan ; Weder, Christoph ; Rowan, Stuart J. / Water-triggered modulus changes of cellulose nanofiber nanocomposites with hydrophobic polymer matrices. In: Macromolecules. 2012 ; Vol. 45, No. 11. pp. 4707-4715.
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