Which is reactive in alkaline solution, boronate ion or boronic acid? Kinetic evidence for reactive trigonal boronic acid in an alkaline solution

Satoshi Iwatsuki, Shihoko Nakajima, Masahiko Inamo, Hideo D. Takagi, Koji Ishihara

    Research output: Contribution to journalArticle

    45 Citations (Scopus)

    Abstract

    That boronic acid is a reactive species toward a diol moiety even in an alkaline solution and that the boronate ion is not very reactive were demonstrated by the estimated upper limit of the rate constants for the reactions of some boronic acids with 2,2′-biphenol and 2,3-dihydroxynaphthalene in a neutral-alkaline solution, which will correct a common misunderstanding in boron chemistry and would renew the idea of effective boronic acid sensor design for carbohydrates.

    Original languageEnglish
    Pages (from-to)354-356
    Number of pages3
    JournalInorganic Chemistry
    Volume46
    Issue number2
    DOIs
    Publication statusPublished - 2007 Jan 22

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    Boronic Acids
    Ions
    acids
    Kinetics
    kinetics
    ions
    Boron
    carbohydrates
    Rate constants
    boron
    Carbohydrates
    chemistry
    sensors
    Sensors

    ASJC Scopus subject areas

    • Inorganic Chemistry

    Cite this

    Which is reactive in alkaline solution, boronate ion or boronic acid? Kinetic evidence for reactive trigonal boronic acid in an alkaline solution. / Iwatsuki, Satoshi; Nakajima, Shihoko; Inamo, Masahiko; Takagi, Hideo D.; Ishihara, Koji.

    In: Inorganic Chemistry, Vol. 46, No. 2, 22.01.2007, p. 354-356.

    Research output: Contribution to journalArticle

    Iwatsuki, Satoshi ; Nakajima, Shihoko ; Inamo, Masahiko ; Takagi, Hideo D. ; Ishihara, Koji. / Which is reactive in alkaline solution, boronate ion or boronic acid? Kinetic evidence for reactive trigonal boronic acid in an alkaline solution. In: Inorganic Chemistry. 2007 ; Vol. 46, No. 2. pp. 354-356.
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    AU - Takagi, Hideo D.

    AU - Ishihara, Koji

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