X-ray absorption spectroscopic study on Bi2Sr2Ca1-xYxCu2O 8+δ (x = 0-1)

Dong Kuk Kim, Jin Ho Choy, Minoru Osada, Masato Kakihana, Masahiro Yoshimura

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Abstract

The X-ray absorption near edge spectra for Bi2Sr2Ca1-xYxCu2O 8+δ (x = 0-1) have been investigated at Cu K- and Bi LIII-edges. Upon the substitution of Y for Ca, overall edge of Cu K-edge XANES spectra shifts towards the lower energy side, indicating the decrease of the formal Cu valence state. The more detailed fine structure was studied from the second-derivative Cu K-edge XANES spectra, and it was suggested that the Cu-O bond distance increases with the substitution of Y3+ for Ca2+. There is no noticeable energy shift in Bi LIII-edge XANES spectra. This is not consistent with the previously reported results. But in our case, invariant spectra upon the substitution of Y might be due to the charge transfer along the Cu-O-Bi bond as well as the amount of the incorporated excess oxygen. The Cu K-edge EXAFS spectra for the present compounds showed average Cu-O bond distance to increase upon the substitution of Y, which is consistent with the Cu K-edge XANES results.

Original languageEnglish
Pages (from-to)291-295
Number of pages5
JournalSolid State Ionics
Volume108
Issue number1-4
Publication statusPublished - 1998 May 1
Externally publishedYes

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Keywords

  • Bi-based superconductor
  • Charge transfer
  • XAS

ASJC Scopus subject areas

  • Electrochemistry
  • Physical and Theoretical Chemistry
  • Energy Engineering and Power Technology
  • Materials Chemistry
  • Condensed Matter Physics

Cite this

Kim, D. K., Choy, J. H., Osada, M., Kakihana, M., & Yoshimura, M. (1998). X-ray absorption spectroscopic study on Bi2Sr2Ca1-xYxCu2O 8+δ (x = 0-1). Solid State Ionics, 108(1-4), 291-295.