X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3

E. Z. Kurmaev, M. A. Korotin, V. R. Galakhov, L. D. Finkelstein, E. I. Zabolotzky, N. N. Efremova, S. Stadler, D. L. Ederer, A. Moewes, S. Bartkowski, M. Neumann, J. Matsuno, Takashi Mizokawa, A. Fujimori, J. Mitchell

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Abstract

The results of measurements of X-ray photoelectron (XPS), X-ray emission (XES) and X-ray absorption spectra and LSDA band structure calculations of Pr0.5Sr0.5MnO3 are presented. The excitation energy dependence of Mn L2,3 and O Kα X-ray emission spectra of Pr0.5Sr0.5MnO3 is measured using tunable synchrotron radiation. Comparing XPS and XES measurements and the LSDA band structure calculations, one concludes that the Mn 3d states are localized near the top of the valence band. Some differences in the Mn 3d-distribution in the upper part of the XPS valence band and Mn L3 XES are due to spin selection rules.

Original languageEnglish
Pages (from-to)793-798
Number of pages6
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume101-103
Publication statusPublished - 1999
Externally publishedYes

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Keywords

  • Electronic structure
  • Manganites
  • X-ray emission resonant spectra
  • X-ray photoelectron spectra

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

Kurmaev, E. Z., Korotin, M. A., Galakhov, V. R., Finkelstein, L. D., Zabolotzky, E. I., Efremova, N. N., Stadler, S., Ederer, D. L., Moewes, A., Bartkowski, S., Neumann, M., Matsuno, J., Mizokawa, T., Fujimori, A., & Mitchell, J. (1999). X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3. Journal of Electron Spectroscopy and Related Phenomena, 101-103, 793-798.