X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3

E. Z. Kurmaev, M. A. Korotin, V. R. Galakhov, L. D. Finkelstein, E. I. Zabolotzky, N. N. Efremova, S. Stadler, D. L. Ederer, A. Moewes, S. Bartkowski, M. Neumann, J. Matsuno, Takashi Mizokawa, A. Fujimori, J. Mitchell

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The results of measurements of X-ray photoelectron (XPS), X-ray emission (XES) and X-ray absorption spectra and LSDA band structure calculations of Pr0.5Sr0.5MnO3 are presented. The excitation energy dependence of Mn L2,3 and O Kα X-ray emission spectra of Pr0.5Sr0.5MnO3 is measured using tunable synchrotron radiation. Comparing XPS and XES measurements and the LSDA band structure calculations, one concludes that the Mn 3d states are localized near the top of the valence band. Some differences in the Mn 3d-distribution in the upper part of the XPS valence band and Mn L3 XES are due to spin selection rules.

Original languageEnglish
Pages (from-to)793-798
Number of pages6
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume101-103
Publication statusPublished - 1999
Externally publishedYes

Fingerprint

Photoelectrons
emission spectra
photoelectrons
X rays
X ray photoelectron spectroscopy
Valence bands
x rays
Band structure
Excitation energy
valence
X ray absorption
Synchrotron radiation
Absorption spectra
synchrotron radiation
absorption spectra
excitation

Keywords

  • Electronic structure
  • Manganites
  • X-ray emission resonant spectra
  • X-ray photoelectron spectra

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

Kurmaev, E. Z., Korotin, M. A., Galakhov, V. R., Finkelstein, L. D., Zabolotzky, E. I., Efremova, N. N., ... Mitchell, J. (1999). X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3. Journal of Electron Spectroscopy and Related Phenomena, 101-103, 793-798.

X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3. / Kurmaev, E. Z.; Korotin, M. A.; Galakhov, V. R.; Finkelstein, L. D.; Zabolotzky, E. I.; Efremova, N. N.; Stadler, S.; Ederer, D. L.; Moewes, A.; Bartkowski, S.; Neumann, M.; Matsuno, J.; Mizokawa, Takashi; Fujimori, A.; Mitchell, J.

In: Journal of Electron Spectroscopy and Related Phenomena, Vol. 101-103, 1999, p. 793-798.

Research output: Contribution to journalArticle

Kurmaev, EZ, Korotin, MA, Galakhov, VR, Finkelstein, LD, Zabolotzky, EI, Efremova, NN, Stadler, S, Ederer, DL, Moewes, A, Bartkowski, S, Neumann, M, Matsuno, J, Mizokawa, T, Fujimori, A & Mitchell, J 1999, 'X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3', Journal of Electron Spectroscopy and Related Phenomena, vol. 101-103, pp. 793-798.
Kurmaev EZ, Korotin MA, Galakhov VR, Finkelstein LD, Zabolotzky EI, Efremova NN et al. X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3. Journal of Electron Spectroscopy and Related Phenomena. 1999;101-103:793-798.
Kurmaev, E. Z. ; Korotin, M. A. ; Galakhov, V. R. ; Finkelstein, L. D. ; Zabolotzky, E. I. ; Efremova, N. N. ; Stadler, S. ; Ederer, D. L. ; Moewes, A. ; Bartkowski, S. ; Neumann, M. ; Matsuno, J. ; Mizokawa, Takashi ; Fujimori, A. ; Mitchell, J. / X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3. In: Journal of Electron Spectroscopy and Related Phenomena. 1999 ; Vol. 101-103. pp. 793-798.
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abstract = "The results of measurements of X-ray photoelectron (XPS), X-ray emission (XES) and X-ray absorption spectra and LSDA band structure calculations of Pr0.5Sr0.5MnO3 are presented. The excitation energy dependence of Mn L2,3 and O Kα X-ray emission spectra of Pr0.5Sr0.5MnO3 is measured using tunable synchrotron radiation. Comparing XPS and XES measurements and the LSDA band structure calculations, one concludes that the Mn 3d states are localized near the top of the valence band. Some differences in the Mn 3d-distribution in the upper part of the XPS valence band and Mn L3 XES are due to spin selection rules.",
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T1 - X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3

AU - Kurmaev, E. Z.

AU - Korotin, M. A.

AU - Galakhov, V. R.

AU - Finkelstein, L. D.

AU - Zabolotzky, E. I.

AU - Efremova, N. N.

AU - Stadler, S.

AU - Ederer, D. L.

AU - Moewes, A.

AU - Bartkowski, S.

AU - Neumann, M.

AU - Matsuno, J.

AU - Mizokawa, Takashi

AU - Fujimori, A.

AU - Mitchell, J.

PY - 1999

Y1 - 1999

N2 - The results of measurements of X-ray photoelectron (XPS), X-ray emission (XES) and X-ray absorption spectra and LSDA band structure calculations of Pr0.5Sr0.5MnO3 are presented. The excitation energy dependence of Mn L2,3 and O Kα X-ray emission spectra of Pr0.5Sr0.5MnO3 is measured using tunable synchrotron radiation. Comparing XPS and XES measurements and the LSDA band structure calculations, one concludes that the Mn 3d states are localized near the top of the valence band. Some differences in the Mn 3d-distribution in the upper part of the XPS valence band and Mn L3 XES are due to spin selection rules.

AB - The results of measurements of X-ray photoelectron (XPS), X-ray emission (XES) and X-ray absorption spectra and LSDA band structure calculations of Pr0.5Sr0.5MnO3 are presented. The excitation energy dependence of Mn L2,3 and O Kα X-ray emission spectra of Pr0.5Sr0.5MnO3 is measured using tunable synchrotron radiation. Comparing XPS and XES measurements and the LSDA band structure calculations, one concludes that the Mn 3d states are localized near the top of the valence band. Some differences in the Mn 3d-distribution in the upper part of the XPS valence band and Mn L3 XES are due to spin selection rules.

KW - Electronic structure

KW - Manganites

KW - X-ray emission resonant spectra

KW - X-ray photoelectron spectra

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