X-ray induced photocurrents at the metal/solution interface

Yuriy V. Tolmachev, In Tae Bae, Daniel Alberto Scherson

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A technique is herein described for the acquisition of X-ray absorption spectra of electrodes fully immersed in an electrolyte solution by monitoring the energy dependence of X-ray induced photocurrents. This novel strategy made it possible to obtain in situ Au LIII-edge X-ray absorption spectra of solid Au electrodes displaying virtually identical features to those recorded simultaneously via X-ray fluorescence. The dependence of the X-ray induced photocurrents on chopping frequency and electrode potential was found to be consistent with a temperature modulation of the rate of the interfacial electron transfer (faradaic heating currents), rather than electron photoemission, as the primary source of the observed effects.

Original languageEnglish
Pages (from-to)7663-7667
Number of pages5
JournalJournal of Physical Chemistry B
Volume104
Issue number32
Publication statusPublished - 2000 Aug 17
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

Fingerprint Dive into the research topics of 'X-ray induced photocurrents at the metal/solution interface'. Together they form a unique fingerprint.

  • Cite this

    Tolmachev, Y. V., Bae, I. T., & Scherson, D. A. (2000). X-ray induced photocurrents at the metal/solution interface. Journal of Physical Chemistry B, 104(32), 7663-7667.