柴田 高範

研究成果

年別の研究成果 1992 2000 2002 2006 2008 2010 2011 2012 2014 2016 2017 2018 2021 2022

• 207 Article
• 6 Chapter
• 6 Review article
• 3 Letter
• 3 その他
  • 2 Comment/debate
  • 1 Short survey

年別の研究成果

年別の研究成果

検索結果

• 2016

  Enantioselective Synthesis of Aminoindan Carboxylic Acid Derivatives by the Catalytic Intramolecular [2+2+2] Cycloaddition of Amino-Acid-Tethered Triynes

  Tahara, Y. K., Obinata, S., Kanyiva, K. S., Shibata, T., Mándi, A., Taniguchi, T. & Monde, K., 2016 3月 1, In: European Journal of Organic Chemistry. 2016, 7, p. 1405-1413 9 p.

  研究成果: Article › 査読

  • cycloaddition 100%
  • carboxylic acids 88%
  • amino acids 71%
  • Cycloaddition 52%
  • Carboxylic Acid 47%
  13 被引用数 (Scopus)

• Enantioselective synthesis of planar-chiral 1,11-dioxa[11]paracyclophane-derived phosphoramidites and their use as chiral ligands

  Hazra, M., Kanyiva, K. S. & Shibata, T., 2016, In: Tetrahedron Asymmetry. 27, 20-21, p. 1081-1087 7 p.

  研究成果: Article › 査読

  • Enantioselectivity 100%
  • Amination 94%
  • alkylation 82%
  • Alkylation 74%
  • Ligands 65%
  4 被引用数 (Scopus)

• Enantioselective Synthesis of Planar-Chiral 1, n -Dioxa[ n ]paracyclophane-Based Phosphites and Their Application as Chiral Ligands

  Shibata, T., Fukai, M., Sekine, R., Hazra, M. & Kanyiva, K. S., 2016 8月 16, In: Synthesis (Germany). 48, 16, p. 2664-2670 7 p., ss-2016-c0168-st.

  研究成果 › 査読

  • Cyclohex-2-Enone 100%
  • Rhodium 96%
  • Alkylation 93%
  • Ligands 83%
  • Palladium 82%
  5 被引用数 (Scopus)

• Iridium-Catalyzed Formal [4 + 1] Cycloaddition of Biphenylenes with Alkenes Initiated by C-C Bond Cleavage for the Synthesis of 9,9-Disubstituted Fluorenes

  Takano, H., Kanyiva, K. S. & Shibata, T., 2016 4月 15, In: Organic Letters. 18, 8, p. 1860-1863 4 p.

  研究成果: Article › 査読

  • Fluorenes 100%
  • Cycloaddition Reaction 74%
  • cycloaddition 72%
  • Iridium 72%
  • Alkenes 70%
  18 被引用数 (Scopus)

• Multi-substituted dibenzophosphole oxide synthesis by the catalytic [2+2+2] cycloaddition of phosphorylbenzene- tethered diynes with various alkynes

  Tahara, Y. K., Sato, T., Matsubara, R., Kanyiva, K. S. & Shibata, T., 2016, In: Heterocycles. 93, 2, p. 685-704 20 p.

  研究成果: Article › 査読

  • Diynes 100%
  • Cycloaddition Reaction 82%
  • Alkynes 80%
  • Oxides 59%
  • Alkyne 42%
  3 被引用数 (Scopus)

• Pt-Catalyzed Enantioselective Cycloisomerization for the Synthesis of Planar-Chiral Ferrocene Derivatives

  Shibata, T., Uno, N., Sasaki, T. & Kanyiva, S. K., 2016 8月 5, In: Journal of Organic Chemistry. 81, 15, p. 6266-6272 7 p.

  研究成果: Article › 査読

  • Cycloisomerization 100%
  • Ferrocene 75%
  • Platinum 56%
  • Ambient Reaction Temperature 42%
  • Catalyst 32%
  42 被引用数 (Scopus)

• Raman study on pentacene:C₆₀ bulk heterojunction films

  Iwasawa, Y., Sasaki, T., Shibata, T. & Furukawa, Y., 2016 5月 1, In: Vibrational Spectroscopy. 84, p. 133-138 6 p.

  研究成果: Article › 査読

  • Pentacene 100%
  • Raman Spectrum 62%
  • Liquid Film 37%
  • Wavenumber 26%
  • Density Functional Theory 15%
  2 被引用数 (Scopus)

• Strategies for the Total Synthesis of Clavicipitic Acid

  Ito, M., Tahara, Y. K. & Shibata, T., 2016, (Accepted/In press) In: Chemistry - A European Journal.

  研究成果: Article › 査読

  • Clavicipitic Acid 100%
  • Azepinoindole 61%
  • Gramine 55%
  • Tryptophan Derivative 51%
  • Ergot Alkaloid 50%
  25 被引用数 (Scopus)
• 2015

  [2+2+2] cycloaddition of sulfanylbenzene-tethered diynes with alkynes for the synthesis of multi-substituted dibenzothiophene derivatives

  Tahara, Y. K., Matsubara, R. & Shibata, T., 2015, In: Heterocycles. 90, 2, p. 1094-1110 17 p.

  研究成果: Article › 査読

  • Diynes 100%
  • dibenzothiophene 91%
  • Cycloaddition Reaction 82%
  • Alkynes 80%
  • Dibenzothiophene 58%
  12 被引用数 (Scopus)

• Asymmetric synthesis of multi-substituted triptycenes via enantioselective alkynylation of 1,5-dibromoanthracene-9,10-dione

  Shibata, T. & Kamimura, Y., 2015 1月 15, In: Tetrahedron Asymmetry. 26, 1, p. 41-45 5 p.

  研究成果: Article › 査読

  • Cycloaddition 100%
  • alkynes 82%
  • Dione 75%
  • Alkynylation 66%
  • Reagents 59%
  10 被引用数 (Scopus)

• Cationic iridium-catalyzed C-H alkylation of 2-substituted pyridine N-oxides with acrylates

  Shibata, T. & Takano, H., 2015 4月 1, In: Organic Chemistry Frontiers. 2, 4, p. 383-387 5 p.

  研究成果: Article › 査読

  • Pyridine N-Oxides 100%
  • Acrylate 60%
  • Alkylation 57%
  • Catalyst 14%
  25 被引用数 (Scopus)

• Enantioselective sp³ C-H alkylation of γ-butyrolactam by a chiral Ir(i) catalyst for the synthesis of 4-substituted γ-amino acids

  Tahara, Y. K., Michino, M., Ito, M., Kanyiva, S. K. & Shibata, T., 2015, In: Chemical Communications. 51, 93, p. 16660-16663 4 p.

  研究成果: Article › 査読

  • Alkylation 100%
  • Olefins 79%
  • Amino acids 79%
  • Lactams 63%
  • Catalysts 56%
  59 被引用数 (Scopus)

• Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation

  Shibata, T., Shizuno, T. & Sasaki, T., 2015 5月 7, In: Chemical Communications. 51, 37, p. 7802-7804 3 p.

  研究成果: Article › 査読

  • Ferrocene 100%
  • Catalysts 86%
  • Catalyst 42%
  91 被引用数 (Scopus)

• Evaluation of strength of soft ground improved by vacuum consolidation

  Shibata, T., Nishimura, S., Fujii, M. & Murakami, A., 2015 3月 1, In: Geotechnical Engineering. 46, 1, p. 95-102 8 p.

  研究成果: Article › 査読

  • preloading 100%
  • ground improvement 98%
  • Consolidation 77%
  • embankment 74%
  • shear strength 71%

• Iridium-catalyzed intramolecular enantioselective c-h alkylation at the C-2 position of N-alkenylindoles

  Shibata, T., Ryu, N. & Takano, H., 2015 4月 13, In: Advanced Synthesis and Catalysis. 357, 6, p. 1131-1135 5 p.

  研究成果: Article › 査読

  • Alkylation 100%
  • Iridium 98%
  • Ligands 88%
  • Indoles 69%
  • Aroyl Group 57%
  61 被引用数 (Scopus)

• Total Synthesis of cis-Clavicipitic Acid from Asparagine via Ir-Catalyzed C-H bond Activation as a Key Step

  Tahara, Y. K., Ito, M., Kanyiva, K. S. & Shibata, T., 2015 8月 1, In: Chemistry - A European Journal. 21, 32, p. 11340-11343 4 p.

  研究成果: Article › 査読

  • (-)-Cis-Clavicipitic Acid 100%
  • Tryptophan Derivative 65%
  • Asparagine 50%
  • Amination 40%
  • Acids 38%
  31 被引用数 (Scopus)
• 2014

  Catalytic [2 + 2 + 2] cycloaddition of benzothiophene dioxides with α,ω-diynes for the synthesis of condensed polycyclic compounds

  Tahara, Y. K., Gake, M., Matsubara, R. & Shibata, T., 2014 11月 21, In: Organic Letters. 16, 22, p. 5980-5983 4 p.

  研究成果: Article › 査読

  • Diynes 100%
  • Polycyclic Compounds 89%
  • benzothiophene 87%
  • Cycloaddition Reaction 82%
  • cycloaddition 80%
  17 被引用数 (Scopus)

• Directed C-H alkenylation of quinoline N-oxides at the C-8 position using a cationic rhodium(I) catalyst

  Shibata, T. & Matsuo, Y., 2014 5月 5, In: Advanced Synthesis and Catalysis. 356, 7, p. 1516-1520 5 p.

  研究成果: Article › 査読

  • Alkenylation 100%
  • Quinoline N-Oxide 62%
  • Rhodium 61%
  • Oxides 33%
  • Catalysts 33%
  68 被引用数 (Scopus)

• Enantioselective synthesis of planar-chiral phosphines with 1,n-dioxa[n]paracyclophane scaffold and their application as chiral ligands

  Kanda, K., Oshima, S., Shizuno, T., Hamanaka, R., Fukai, M. & Shibata, T., 2014, In: Heterocycles. 8, 2, p. 1355-1370 16 p.

  研究成果: Article › 査読

  • Phosphines 100%
  • butyllithium 52%
  • Phosphine 42%
  • Sparteine 39%
  • Imines 35%
  6 被引用数 (Scopus)

• Highly chemo-, enantio-, and regioselective synthesis of α,α-disubstituted furanones by Cu-catalyzed conjugate addition

  Endo, K., Yakeishi, S., Takayama, R. & Shibata, T., 2014 7月 14, In: Chemistry - A European Journal. 20, 29, p. 8893-8897 5 p.

  研究成果: Article › 査読

  • Ketoester 100%
  • Reagents 78%
  • Acyclic Compound 50%
  • Cyclic Compound 41%
  • Ambient Reaction Temperature 36%
  15 被引用数 (Scopus)

• Ir(III)-catalyzed C7-position-selective oxidative C -H alkenylation of indolines with alkenes in air

  Pan, S., Wakaki, T., Ryu, N. & Shibata, T., 2014 5月, In: Chemistry - An Asian Journal. 9, 5, p. 1257-1260 4 p.

  研究成果: Article › 査読

  • indoline 100%
  • Alkenes 85%
  • Alkenylation 75%
  • Indoline 68%
  • Carbamoyl Group 56%
  58 被引用数 (Scopus)

• Iridium(I)-catalyzed direct C-H bond alkylation of the C-7 position of indolines with alkenes

  Pan, S., Ryu, N. & Shibata, T., 2014 3月 24, In: Advanced Synthesis and Catalysis. 356, 5, p. 929-933 5 p.

  研究成果: Article › 査読

  • Alkylation 100%
  • Iridium 98%
  • Indoline 84%
  • Olefins 79%
  • Atoms 69%
  83 被引用数 (Scopus)

• Iridium-catalyzed enantioselective C-H alkylation of ferrocenes with alkenes using chiral diene ligands

  Shibata, T. & Shizuno, T., 2014 5月 19, In: Angewandte Chemie - International Edition. 53, 21, p. 5410-5413 4 p.

  研究成果: Article › 査読

  • Alkylation 100%
  • Iridium 98%
  • Ferrocenes 90%
  • Ligands 88%
  • Olefins 79%
  165 被引用数 (Scopus)

• One-pot cross-coupling of diborylmethane for the synthesis of dithienylmethane derivatives

  Endo, K., Ishioka, T. & Shibata, T., 2014 9月, In: Synlett. 25, 15, p. 2184-2188 5 p., st-2014-u0515-l.

  研究成果: Article › 査読

  • Suzuki-Miyaura Coupling 100%
  • Cross-Coupling Reaction 90%
  • Reaction Yield 36%
  16 被引用数 (Scopus)

• Synthesis of macrocyclic heteroarylenes by consecutive inter- and intramolecular cycloadditions of thiophenylene-tethered triynes

  Shibata, T., Fujimoto, M. & Otani, T., 2014 11月 11, In: Tetrahedron. 70, 45, p. 8453-8461 9 p.

  研究成果: Article › 査読

  • Bistris 100%
  • Cycloaddition Reaction 89%
  • Intramolecular Cycloaddition 74%
  • Dimerization 60%
  • Trimer 52%
  7 被引用数 (Scopus)

• Synthesis of multicyclic heterocycles initiated by c-h bond activation along with "rollover" using a Rh(III) catalyst

  Shibata, T. & Takayasu, S., 2014 11月 1, In: Heteroatom Chemistry. 25, 5, p. 379-388 10 p.

  研究成果: Article › 査読

  • Pivalate 100%
  • Alkyne 61%
  • Catalyst 59%
  • Acetate 49%
  • Sodium Atom 44%
  15 被引用数 (Scopus)
• 2013

  Asymmetric Cycloaddition Reactions

  Shibata, T., 2013 8月, Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications. Elsevier Ltd, Vol. 6. p. 249-269 21 p.

  研究成果: Chapter

  • Cycloaddition 100%
  • Chirality 36%
  • Lewis Acid 35%
  • Transition Element 28%
  3 被引用数 (Scopus)

• BINAM- mono -PHOS as new entry for multinuclear copper catalysts in asymmetric conjugate addition of organozinc reagents

  Endo, K., Takayama, R. & Shibata, T., 2013 4月 25, In: Synlett. 24, 9, p. 1155-1159 5 p., ST-2013-U0225-L.

  研究成果: Article › 査読

  • Nitrogen Atom 75%
  • Enantiomer 70%
  • Ligand 39%
  • Catalyst 37%
  12 被引用数 (Scopus)

• Cationic iridium-catalyzed synthesis initiated by the cleavage of C-H, N-H, and C-O bonds

  Shibata, T., Tsuchikama, K. & Pan, S., 2013, In: Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry. 71, 11, p. 1182-1194 13 p.

  研究成果: Article › 査読

  • Alkylation 100%
  • Cleavage 80%
  • Hydroamination 75%
  • Amine 75%
  • Benzofuran 70%
  9 被引用数 (Scopus)

• Effect of multinuclear copper/aluminum complexes in highly asymmetric conjugate addition of trimethylaluminum to acyclic enones

  Endo, K., Hamada, D., Yakeishi, S. & Shibata, T., 2013 1月 7, In: Angewandte Chemie - International Edition. 52, 2, p. 606-610 5 p.

  研究成果: Article › 査読

  • Enantioselectivity 91%
  • Copper 73%
  • Aluminum 69%
  • Carbon 68%
  • Ketones 64%
  51 被引用数 (Scopus)

• Functionalized BINOL-mono-PHOS for multinuclear Cu-catalysts in asymmetric conjugate addition of organozinc reagents

  Endo, K., Yakeishi, S., Hamada, D. & Shibata, T., 2013 5月 15, In: Chemistry Letters. 42, 5, p. 547-549 3 p.

  研究成果: Article › 査読

  • Cyclohexenone 63%
  • Hydroxy Group 46%
  • Enantioselectivity 39%
  • Ligand 19%
  • Reaction Yield 18%
  14 被引用数 (Scopus)

• Ir(I)-catalyzed synthesis of N-substituted pyridones from 2-alkoxypyridines via C-O bond cleavage

  Pan, S., Ryu, N. & Shibata, T., 2013 4月 19, In: Organic Letters. 15, 8, p. 1902-1905 4 p.

  研究成果: Article › 査読

  • Pyridones 100%
  • Sodium Acetate 88%
  • Pyridone 78%
  • Hydrogen 69%
  • acetates 64%
  36 被引用数 (Scopus)

• Recent advances in iridium-catalyzed alkylation of C-H and N-H bonds

  Pan, S. & Shibata, T., 2013 4月 5, In: ACS Catalysis. 3, 4, p. 704-712 9 p.

  研究成果 › 査読

  • Alkylation 100%
  • Iridium 98%
  • Allylation 81%
  • Olefins 39%
  • Carbonates 37%
  271 被引用数 (Scopus)
• 2012

  Asymmetric ortho-lithiation of 1,n-dioxa[n]paracyclophane derivatives for the generation of planar chirality

  Kanda, K., Hamanaka, R., Endo, K. & Shibata, T., 2012 2月 4, In: Tetrahedron. 68, 5, p. 1407-1416 10 p.

  研究成果: Article › 査読

  • Sparteine 100%
  • Electrophile 59%
  • Chirality 55%
  • Dilithiation 49%
  • Multi-Step Reaction 39%
  27 被引用数 (Scopus)

• BARF-catalyzed C-H bond alkenylation and alkylation of ferrocenes

  Takebayashi, S. & Shibata, T., 2012 6月 11, In: Organometallics. 31, 11, p. 4114-4117 4 p.

  研究成果: Article › 査読

  • alkylation 100%
  • ferrocenes 84%
  • Alkenylation 83%
  • Ferrocenes 81%
  • Alkylation 51%
  73 被引用数 (Scopus)

• Cationic iridium-catalyzed enantioselective activation of secondary sp ³ C-H bond adjacent to nitrogen atom

  Pan, S., Matsuo, Y., Endo, K. & Shibata, T., 2012 11月 4, In: Tetrahedron. 68, 44, p. 9009-9015 7 p.

  研究成果: Article › 査読

  • Pyridines 100%
  • Alkynes 90%
  • Iridium 88%
  • Alkenes 86%
  • Methylene Group 59%
  82 被引用数 (Scopus)

• Cross coupling between sp ³-carbon and sp ³-carbon using a diborylmethane derivative at room temperature

  Endo, K., Ohkubo, T., Ishioka, T. & Shibata, T., 2012 5月 18, In: Journal of Organic Chemistry. 77, 10, p. 4826-4831 6 p.

  研究成果: Article › 査読

  • Benzyl Halide 100%
  • Suzuki-Miyaura Coupling 78%
  • Cross-Coupling Reaction 71%
  • Chemoselectivity 69%
  • Halide 53%
  85 被引用数 (Scopus)

• Detour and direct induction of methyl-containing chiral centers via catalytic C-H or C-C bond formation

  Endo, K. & Shibata, T., 2012, In: Synthesis. 44, 10, p. 1427-1452 26 p.

  研究成果 › 査読

  • Methylation 100%
  • Friedel-Crafts reaction 47%
  • Hydroformylation 37%
  • Alkylation 30%
  • Trifluoromethylation 27%
  12 被引用数 (Scopus)

• Enantioselective synthesis of tripodal cyclophanes and pyridinophanes by intramolecular [2+2+2] cycloaddition

  Shibata, T., Miyoshi, M., Uchiyama, T., Endo, K., Miura, N. & Monde, K., 2012 3月 25, In: Tetrahedron. 68, 12, p. 2679-2686 8 p.

  研究成果: Article › 査読

  • Diynes 100%
  • Cycloaddition Reaction 82%
  • Alkynes 80%
  • 2-aminophenol 45%
  • Alkyne 42%
  27 被引用数 (Scopus)

• Facile synthesis of cyclic polyphenylenes by consecutive inter- and intramolecular cycloadditions of ortho -, meta -, and para -phenylene-tethered triynes

  Shibata, T., Fujimoto, M., Hirashima, H., Chiba, T. & Endo, K., 2012, In: Synthesis (Germany). 44, 21, p. 3269-3284 16 p., SS-2012-Z0614-FA.

  研究成果: Article › 査読

  • Hexaphenylene 100%
  • Cycloaddition 93%
  • Dimers 69%
  • Intramolecular Cycloaddition 64%
  • Octaphenylene 51%
  24 被引用数 (Scopus)

• Highly enantioselective synthesis of silahelicenes using Ir-catalyzed [2+2+2] cycloaddition

  Shibata, T., Uchiyama, T., Yoshinami, Y., Takayasu, S., Tsuchikama, K. & Endo, K., 2012 1月 9, In: Chemical Communications. 48, 9, p. 1311-1313 3 p.

  研究成果: Article › 査読

  • Cycloaddition 100%
  • Silole 37%
  83 被引用数 (Scopus)

• Ir(I)-catalyzed C-H bond alkylation of C2-position of indole with alkenes: Selective synthesis of linear or branched 2-alkylindoles

  Pan, S., Ryu, N. & Shibata, T., 2012 10月 24, In: Journal of the American Chemical Society. 134, 42, p. 17474-17477 4 p.

  研究成果: Article › 査読

  • Alkenes 100%
  • Alkylation 95%
  • Iridium 93%
  • indole 83%
  • Olefins 76%
  184 被引用数 (Scopus)

• Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines

  Pan, S., Endo, K. & Shibata, T., 2012 2月 3, In: Organic Letters. 14, 3, p. 780-783 4 p.

  研究成果: Article › 査読

  • Alkenes 100%
  • Styrene 90%
  • Hydroamination 82%
  • alkenes 81%
  • amines 75%
  70 被引用数 (Scopus)

• Multinuclear Cu-catalysts based on SPINOL-PHOS in asymmetric conjugate addition of organozinc reagents

  Endo, K., Hamada, D., Yakeishi, S., Ogawa, M. & Shibata, T., 2012 5月 4, In: Organic Letters. 14, 9, p. 2342-2345 4 p.

  研究成果: Article › 査読

  • reagents 100%
  • ligands 88%
  • catalysts 81%
  • Ligands 62%
  • Phosphorus 46%
  35 被引用数 (Scopus)

• Non Chiral Pauson-Khand Reaction

  Shibata, T., 2012 3月 12, Pauson-Khand Reaction: Scope, Variations and Applications. John Wiley and Sons, p. 49-68 20 p.

  研究成果: Chapter

• One-pot synthesis of symmetrical and unsymmetrical diarylmethanes via diborylmethane

  Endo, K., Ishioka, T., Ohkubo, T. & Shibata, T., 2012 9月 7, In: Journal of Organic Chemistry. 77, 17, p. 7223-7231 9 p.

  研究成果: Article › 査読

  • Diarylmethane 100%
  • One Pot Reaction 58%
  • Suzuki-Miyaura Coupling 36%
  • Cross-Coupling Reaction 32%
  • Reaction Yield 13%
  61 被引用数 (Scopus)

• Pauson-Khand reaction

  Shibata, T., 2012 1月 1, Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Three Volumes. Wiley-Blackwell, p. 1287-1305 19 p.

  研究成果: Chapter
  1 被引用数 (Scopus)

• Reversal in enantioselectivity induced by achiral alcohols in asymmetric autocatalysis in the presence of a chiral diol as a chiral initiator

  Shibata, T., Tarumi, H., Kawasaki, T. & Soai, K., 2012 7月 31, In: Tetrahedron Asymmetry. 23, 14, p. 1023-1027 5 p.

  研究成果: Article › 査読

  • Enantioselectivity 100%
  • autocatalysis 77%
  • Autocatalysis 64%
  • initiators 63%
  • Alcohols 54%
  12 被引用数 (Scopus)

• Rh(III)-catalyzed C-H bond activation along with "rollover" for the synthesis of 4-azafluorenes

  Shibata, T., Takayasu, S., Yuzawa, S. & Otani, T., 2012 10月 5, In: Organic Letters. 14, 19, p. 5106-5109 4 p.

  研究成果: Article › 査読

  • pyridine 100%
  • pyridines 96%
  • activation 61%
  • synthesis 55%
  • Chemical Transformation 48%
  56 被引用数 (Scopus)

• Rh(III)-catalyzed directed C-H bond amidation of ferrocenes with isocyanates

  Takebayashi, S., Shizuno, T., Otani, T. & Shibata, T., 2012 10月 29, In: Beilstein Journal of Organic Chemistry. 8, p. 1844-1848 5 p.

  研究成果: Article › 査読

  • Ferrocenes 100%
  • Isocyanate 74%
  • Diastereoselectivity 37%
  • Reaction Yield 15%
  39 被引用数 (Scopus)