1,2-Bis(ferrocenyl)-substituted distibene and dibismuthene: Sb=Sb and Bi=Bi units as π spacers between two ferrocenyl units

Michiyasu Sakagami; Takahiro Sasamori; Heisuke Sakai; Yukio Furukawa; Norihiro Tokitoh

doi:10.1002/asia.201201227

1,2-Bis(ferrocenyl)-substituted distibene and dibismuthene: Sb=Sb and Bi=Bi units as π spacers between two ferrocenyl units

Michiyasu Sakagami, Takahiro Sasamori^*, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

35 被引用数 (Scopus)

抄録

Pi in the sky: 1,2-bis(ferrocenyl)distibene and 1,2-bis(ferrocenyl) dibismuthene derivatives, where two bulky ferrocenyl units are bridged by a Sb=Sb and Bi=Bi π spacer, have been synthesized as a new family of novel d-π conjugated systems. Their molecular structures, spectroscopic behavior, and electrochemical properties reveal the Sb=Sb and Bi=Bi units to be effective π-electron spacers.

本文言語	English
ページ（範囲）	690-693
ページ数	4
ジャーナル	Chemistry - An Asian Journal
巻	8
号	4
DOI	https://doi.org/10.1002/asia.201201227
出版ステータス	Published - 2013 4月

ASJC Scopus subject areas

生化学
有機化学

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10.1002/asia.201201227

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引用スタイル

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abstract = "Pi in the sky: 1,2-bis(ferrocenyl)distibene and 1,2-bis(ferrocenyl) dibismuthene derivatives, where two bulky ferrocenyl units are bridged by a Sb=Sb and Bi=Bi π spacer, have been synthesized as a new family of novel d-π conjugated systems. Their molecular structures, spectroscopic behavior, and electrochemical properties reveal the Sb=Sb and Bi=Bi units to be effective π-electron spacers.",

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AU - Sasamori, Takahiro

AU - Sakai, Heisuke

AU - Furukawa, Yukio

AU - Tokitoh, Norihiro

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KW - sandwich complexes

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