2,6,10-Tris(bithiophenyl)triphenylene: Synthesis and high-spin alignment in its p-doped radical derivative

Takeshi Ibe, Hiroaki Umeda, Hiroyuki Nishide*

*この研究の対応する著者

研究成果: Article査読

4 被引用数 (Scopus)

抄録

2,6,10-Tris[5′-(5-hexyloxyphenyl-2,2′-bithiophenyl)]-3,7,11-tris(hexyloxy)tripheneylene (2) was designed and synthesized as a π-conjugated platform to produce its tris(cationic radical) derivative (1) in a non-Kekulé and nondisjoint fashion. An electrochemical study revealed the chemically reversible redox property of 2. Gaseous antimony pentachloride-doping of 2 dispersed in a polystyrene matrix gave its cationic radical. It was chemically stable with a half-life >2 weeks and displayed a triplet ground state based on an ESR measurement. A high-spin state with S = 3/2 for 1 was proved by the magnetization and magnetic susceptibility.

本文言語English
ページ(範囲)788-791
ページ数4
ジャーナルSynthetic Metals
159
9-10
DOI
出版ステータスPublished - 2009 5

ASJC Scopus subject areas

  • 機械工学
  • 材料力学
  • 材料化学
  • 金属および合金
  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学

フィンガープリント

「2,6,10-Tris(bithiophenyl)triphenylene: Synthesis and high-spin alignment in its p-doped radical derivative」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル