3D printing phosphonium ionic liquid networks with mask projection microstereolithography

Alison R. Schultz, Philip M. Lambert, Nicholas A. Chartrain, David M. Ruohoniemi, Zhiyang Zhang, Chainika Jangu, Musan Zhang, Christopher B. Williams, Timothy Edward Long

研究成果: Article

54 被引用数 (Scopus)

抄録

Photopolymerization coupled with mask projection microstereolithography successfully generated various 3D printed phosphonium polymerized ionic liquids (PILs) with low UV light intensity requirements and high digital resolution. Varying phosphonium monomer concentration, diacrylate cross-linking comonomer, and display images enabled precise 3D design and polymeric properties. The resulting cross-linked phosphonium PIL objects exhibited a synergy of high thermal stability, tunable glass transition temperature, optical clarity, and ion conductivity, which are collectively well-suited for emerging electro-active membrane technologies. Ion conductivity measurements on printed objects revealed a systematic progression in conductivity with ionic liquid monomer content, and thermal properties and solvent extraction demonstrated the formation of a polymerized ionic liquid network, with gel fractions exceeding 95%.

本文言語English
ページ(範囲)1205-1209
ページ数5
ジャーナルACS Macro Letters
3
11
DOI
出版ステータスPublished - 2014 11 18
外部発表はい

ASJC Scopus subject areas

  • Polymers and Plastics
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

フィンガープリント 「3D printing phosphonium ionic liquid networks with mask projection microstereolithography」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル