A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands

Yuji Kikukawa; Yoshiyuki Kuroda; Kosuke Suzuki; Mitsuhiro Hibino; Kazuya Yamaguchi; Noritaka Mizuno

doi:10.1039/c2cc37591e

A discrete octahedrally shaped [Ag₆]⁴⁺ cluster encapsulated within silicotungstate ligands

Yuji Kikukawa, Yoshiyuki Kuroda, Kosuke Suzuki, Mitsuhiro Hibino, Kazuya Yamaguchi, Noritaka Mizuno^*

^*この研究の対応する著者

研究成果: Article › 査読

53 被引用数 (Scopus)

抄録

By the reaction of TBA₄H₄[γ-SiW ₁₀O₃₆] (TBA = tetra-n-butylammonium) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag₆] ⁴⁺ cluster, TBA₈[Ag₆(γ-H ₂SiW₁₀O₃₆)₂]·5H₂O, could be synthesized, and the molecular structure was determined. This journal is

本文言語	English
ページ（範囲）	376-378
ページ数	3
ジャーナル	Chemical Communications
巻	49
号	4
DOI	https://doi.org/10.1039/c2cc37591e
出版ステータス	Published - 2013 1月 14
外部発表	はい

ASJC Scopus subject areas

金属および合金
材料化学
表面、皮膜および薄膜
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
触媒
化学 (全般)

文献へのアクセス

10.1039/c2cc37591e

他のファイルとリンク

引用スタイル

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AU - Kikukawa, Yuji

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AU - Yamaguchi, Kazuya

AU - Mizuno, Noritaka

PY - 2013/1/14

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