A general catalyst for the β-selective C - H bond arylation of thiophenes with iodoarenes

Kirika Ueda, Shuichi Yanagisawa, Junichiro Yamaguchi, Kenichiro Itami*

*この研究の対応する著者

研究成果: Article査読

198 被引用数 (Scopus)

抄録

Open access: The normally less-reactive β position of thiophenes was previously inaccessible to direct functionalization. However, the β selectivity observed with the catalytic system PdCl2/P{OCH(CF 3)2}3/Ag2CO3 in the arylation of thiophenes with iodoarenes (see scheme) is a remarkably general phenomenon applicable to unsubstituted, monosubstituted, and disubstituted thiophene derivatives, as well as thiophene-containing fused aromatic compounds.

本文言語English
ページ(範囲)8946-8949
ページ数4
ジャーナルAngewandte Chemie - International Edition
49
47
DOI
出版ステータスPublished - 2010 11 15
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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