A hybrid lithium oxalate-phosphinate salt

Andrew R. Shaffer; Nihal Deligonul; Daniel Alberto Scherson; John D. Protasiewicz

doi:10.1021/ic1018532

A hybrid lithium oxalate-phosphinate salt

Andrew R. Shaffer, Nihal Deligonul, Daniel Alberto Scherson, John D. Protasiewicz

研究成果: Article › 査読

11 被引用数 (Scopus)

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The novel organophosphorus-containing lithium salt Li(THF)[(C ₂O₄)B(O₂PPh₂)₂] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C₂O₄) B(O₂PPh₂)₂]₂·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.

本文言語	English
ページ（範囲）	10756-10758
ページ数	3
ジャーナル	Inorganic Chemistry
巻	49
号	23
DOI	https://doi.org/10.1021/ic1018532
出版ステータス	Published - 2010 12 6
外部発表	はい

ASJC Scopus subject areas

無機化学
物理化学および理論化学

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abstract = "The novel organophosphorus-containing lithium salt Li(THF)[(C 2O4)B(O2PPh2)2] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C2O4) B(O2PPh2)2]2·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.",

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AB - The novel organophosphorus-containing lithium salt Li(THF)[(C 2O4)B(O2PPh2)2] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C2O4) B(O2PPh2)2]2·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.

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A hybrid lithium oxalate-phosphinate salt

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