抄録
The novel organophosphorus-containing lithium salt Li(THF)[(C 2O4)B(O2PPh2)2] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C2O4) B(O2PPh2)2]2·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.
本文言語 | English |
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ページ(範囲) | 10756-10758 |
ページ数 | 3 |
ジャーナル | Inorganic Chemistry |
巻 | 49 |
号 | 23 |
DOI | |
出版ステータス | Published - 2010 12月 6 |
外部発表 | はい |
ASJC Scopus subject areas
- 無機化学
- 物理化学および理論化学