A kaolinite-NMF-methanol intercalation compound as a versatile intermediate for further intercalation reaction of kaolinite

Yoshihiko Komori, Yoshiyuki Sugahara, Kazuyuki Kuroda*

*この研究の対応する著者

研究成果: Article査読

89 被引用数 (Scopus)

抄録

A kaolinite-organic intercalation compound containing methanol was proved to be a versatile host for further displacement reaction with alkylamines. Kaolinite-organic intercalation compounds with polar molecules, such as N-methylformamide (NMF) and formamide, were used as the starting materials. After stirring the kaolinite-NMF intercalation compound with methanol, the basal spacing increased to 1.11 nm. The 13C MAS NMR result of the product indicated that methanol was intercalated into kaolinite by partial displacement with NMF. By use of the methanol-treated kaolinite intercalation compound as the intermediate, alkylamines were intercalated into the interlayer space of kaolinite by displacing with methanol.

本文言語English
ページ(範囲)930-934
ページ数5
ジャーナルJournal of Materials Research
13
4
DOI
出版ステータスPublished - 1998 4月

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学
  • 材料力学
  • 機械工学

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