A new one-pot method for α,α-diallylation of ketones based on the palladium-catalyzed reaction of allylic carbonates and allyl β-keto carboxylates under neutral conditions

Isao Shimizu*, Yukihiro Ohashi, Jiro Tsuji

*この研究の対応する著者

    研究成果: Article査読

    13 被引用数 (Scopus)

    抄録

    A new method for α,α-diallylation of ketones catalyzed by palladium-phosphine complexes under neutral conditions has been developed. Allylation of β-keto carboxylates with allylic carbonates, followed by the decarboxylation-allylation as a one-pot reaction affords diallylated ketones in good yields.

    本文言語English
    ページ(範囲)3865-3868
    ページ数4
    ジャーナルTetrahedron Letters
    24
    36
    DOI
    出版ステータスPublished - 1983

    ASJC Scopus subject areas

    • 生化学
    • 有機化学
    • 創薬

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