A novel palladium-catalyzed preparative method of α,β-unsaturated ketones and aldehydes from saturated ketones and aldehydes via their silyl enol ethers

Jiro Tsuji, Ichiro Minami, Isao Shimizu

    研究成果: Article査読

    60 被引用数 (Scopus)

    抄録

    Silyl enol ethers prepared from saturated ketones and aldehydes can be converted to α,β-unsaturated ketones and aldehydes by the reaction of allyl carbonate in the presence of palladium-phosphine complexes as a catalyst. The selection of solvent is crucial and nitriles are most effective as the solvent.

    本文言語English
    ページ(範囲)5635-5638
    ページ数4
    ジャーナルTetrahedron Letters
    24
    50
    DOI
    出版ステータスPublished - 1983

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

    フィンガープリント 「A novel palladium-catalyzed preparative method of α,β-unsaturated ketones and aldehydes from saturated ketones and aldehydes via their silyl enol ethers」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

    引用スタイル