A pH-stable ruthenium(II)-based sensing system for dissolved dinitrogen

Tetsuro Kizaki, Takeru Abe, Takahiro Matsumoto, Seiji Ogo*

*この研究の対応する著者

    研究成果: Article査読

    3 被引用数 (Scopus)

    抄録

    Building on a previous design for a Ru-based dissolved N 2 sensor, we report an adaptation that allows for reversible data storage. The N 2 complex can be "fixed" and made stable across a range of pHs by the substitution of OH - with F - to form [Ru II(F)(TMC)(N 2)] + (1, TMC= l,4,8,11-tetramethyl-l,4,8,11tetraazacyclotetradecane). The addition of Ca2+ and irradiation with light at high pH removes the F -, thereby regenerating the sensor in its reversible configuration.

    本文言語English
    ページ(範囲)128-129
    ページ数2
    ジャーナルChemistry Letters
    39
    2
    DOI
    出版ステータスPublished - 2010

    ASJC Scopus subject areas

    • 化学 (全般)

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