A remarkable 14-nuclear Re8VAg6I coordination oligomer derived from a 2D (Re2VAg2I)n coordination polymer with D-penicillaminate

Takumi Konno*, Yuichi Shimazaki, Tadashi Yamaguchi, Tasuku Ito, Masakazu Hirotsu

*この研究の対応する著者

研究成果: Article査読

26 被引用数 (Scopus)

抄録

ReV polymer/oligomer switching: The aggregation of ReV otahedra, [ReO-(D-pen-N,O)(D-pen-N,O,S)]- (D-H2pen=D-penicillamine), assisted by AgI ions, leads to the formation of a 2D (Re2VAg2I)n coordination polymer 1, which is converted into a Re8VAg6I coordination oligomer 2 (see picture; Ag green, S yellow, Re purple, O red, N blue). While 1 results from the self-assembly of Re2VAg2I units through Ag-O coordination bonding, the self-assembly of Re8VAg6I molecules in 2 is through COOH ⋯ OOC hydrogen bonding.

本文言語English
ページ(範囲)4711-4715
ページ数5
ジャーナルAngewandte Chemie - International Edition
41
24
DOI
出版ステータスPublished - 2002 12月 16
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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