A rock-salt-like lattice structure consisting of monocationic and monoanionic AuIAgICuII supramolecular cages of D-penicillaminate

Atsushi Toyota*, Tadashi Yamaguchi, Asako Igashira-Kamiyama, Tatsuya Kawamoto, Takumi Konno

*この研究の対応する著者

研究成果: Article査読

54 被引用数 (Scopus)

抄録

All three coinage metals are present in the supramolecular compound created from D-penicillamine (D-H2pen) by stepwise reaction with Au I, AgI, and CuII in the presence of Cl -. In this compound, 20-nuclear monocationic [Au6Ag 8Cu6Cl-(H2O)5(D-pen) 12]+ and 21-nuclear monoanionic [Au6Ag 9Cu6Cl4(H2O)6(D-pen) 12]- (see picture) supramolecular cages, each of which accommodates a Cl- ion (green), are linked so as to form a giant rock-salt-like lattice structure.

本文言語English
ページ(範囲)1088-1092
ページ数5
ジャーナルAngewandte Chemie - International Edition
44
7
DOI
出版ステータスPublished - 2005 2月 4

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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