A rotaxane-like complex with controlled-release characteristics

Sheng Hsien Chiu, Stuart J. Rowan, Stuart J. Cantrill, Peter T. Glink, Robin L. Garrell, J. Fraser Stoddart

研究成果: Article査読

48 被引用数 (Scopus)

抄録

(matrix presented) A rotaxane-like complex, based on a dumbbell-shaped component containing an NH2+ recognition site for a [25]crown-8 ring component and a slippage stopper in the form of a p-(tert-butyl)phenyl group, has been synthesized by a "threading-followed-by-stoppering" approach. The half-life for dissociation of this complex, which is very sensitive to its environment, can be varied from minutes to months by changing the temperature and the polarity of the solvent.

本文言語English
ページ(範囲)3631-3634
ページ数4
ジャーナルOrganic Letters
2
23
出版ステータスPublished - 2000 11 16
外部発表はい

ASJC Scopus subject areas

  • Molecular Medicine

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