A triplet biradical with double bidentate sites based on tert-butyl pyridyl nitroxide as a candidate for strong ferromagnetic couplers

Atsushi Okazawa*, Yutaro Terakado, Takayuki Ishida, Norimichi Kojima

*この研究の対応する著者

研究成果: Article査読

9 被引用数 (Scopus)

抄録

We synthesised a new biradical, 34bpybNO, having two chelating radical sites and demonstrated its crystal structure and ground triplet nature. Frozen-solution magnetic measurement and electron spin resonance results revealed a strong intramolecular ferromagnetic coupling reaching 2J/kB = ∼+170 K, which is supported by density functional theory calculations.

本文言語English
ページ(範囲)17874-17878
ページ数5
ジャーナルNew Journal of Chemistry
42
22
DOI
出版ステータスPublished - 2018
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 材料化学

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