A versatile route to polythiophenes with functional pendant groups using alkyne chemistry

Xiao Huang, Li Yang, Rikard Emanuelsson, Jonas Bergquist, Maria Strømme, Martin Sjödin, Adolf Gogoll

研究成果: Article査読

8 被引用数 (Scopus)

抄録

A new versatile polythiophene building block, 3-(3,4-ethylenedioxythiophene)prop-1-yne (pyEDOT) (3), is prepared from glycidol in four steps in 28% overall yield. pyEDOT features an ethynyl group on its ethylenedioxy bridge, allowing further functionalization by alkyne chemistry. Its usefulness is demonstrated by a series of functionalized polythiophene derivatives that were obtained by pre- and post-electropolymerization transformations, provided by the synthetic ease of the Sonogashira coupling and click chemistry.

本文言語English
ページ(範囲)2682-2688
ページ数7
ジャーナルBeilstein Journal of Organic Chemistry
12
DOI
出版ステータスPublished - 2016 12 9
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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