Acyclic and cyclic di- and tri(4-oxyphenyl-1,2-phenyleneethynylene)s: Their synthesis and ferromagnetic spin interaction

Hiroyuki Nishide, Masahiro Takahashi, Junichi Takashima, Yong Jin Pu, Eishun Tsuchida

研究成果: Article

28 引用 (Scopus)

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A new set of π-conjugated and alternant but non-Kekule-type di- and tri(1,2-phenyleneethynylene)s pendantly substituted with phenoxyl radicals at the 4 positions (1a, 2a, and 3a) was synthesized. The synthesis of these acyclic and cyclic compounds was achieved through the head-to-tail coupling of 2-bromo(or -iodo)-4-[3',5'-di-tert-butyl-4'-trimethylsiloxyl(or - hydroxy)phenyl]-1-ethynylbenzenes. The di- and triphenoxyl compounds (1a, and 2a and 3a) were triplet and quartet at the ground state, respectively, which was ascribed to a ferromagnetic coupling effect of the diphenyl ethynylene bridge for the pendant phenoxyls' spins. The cyclic π-conjugation in 3a exhibited a stronger effect on the spin alignment.

元の言語English
ページ(範囲)7375-7380
ページ数6
ジャーナルJournal of Organic Chemistry
64
発行部数20
DOI
出版物ステータスPublished - 1999 10 1

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ASJC Scopus subject areas

  • Organic Chemistry

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