Allylic carbonates. Efficient allylating agents of carbonucleophiles in palladium-catalyzed reactions under neutral conditions

Jiro Tsuji*, Isao Shimizu, Ichiro Minami, Yukihiro Ohashi, Teruo Sugiura, Kazuhiko Takahashi

*この研究の対応する著者

    研究成果査読

    243 被引用数 (Scopus)

    抄録

    Allylation of β-keto esters or malonates was carried out in good yields under neutral conditions by using allylic carbonates in the presence of palladium-phosphine catalyst. Although simple ketones, esters, nitriles, and sulfones hardly react with allylic carbonates, α-alkenyl or α-aryl ketones, esters, nitriles, and sulfones were also allylated by using palladium-bis(diphenylphosphino)ethane catalyst under neutral conditions.

    本文言語English
    ページ(範囲)1523-1529
    ページ数7
    ジャーナルJournal of Organic Chemistry
    50
    9
    出版ステータスPublished - 1985

    ASJC Scopus subject areas

    • 有機化学

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