An Air- and Water-Stable B4N4-Heteropentalene Serving as a Host Material for a Phosphorescent OLED

Junki Kashida, Yoshiaki Shoji*, Yasuhiro Ikabata, Hideo Taka, Hayato Sakai, Taku Hasobe, Hiromi Nakai, Takanori Fukushima

*この研究の対応する著者

研究成果: Article査読

抄録

Replacement of the carbon–carbon bonds of antiaromatic compounds with polar boron–nitrogen bonds often provides isoelectronic BN compounds with excellent thermodynamic stability and interesting photophysical properties. By this element-substitution strategy, we synthesized a new B4N4-heteropentalene derivative, 1, which is fully substituted with mesityl groups. Owing to kinetic protection by the sterically bulky substituents, 1 is remarkably stable toward air and even water. Single-crystal X-ray analysis of 1 revealed the bonding characteristics of the B4N4-heteropentalene structure. In a glassy matrix, 1 emitted short-wavelength phosphorescence with an onset at 350 nm, indicating that the triplet energy is substantially high. DFT calculations reasonably explained the ground- and excited-state electronic structures of 1 as well as its emission properties. Motivated by the high-energy triplet state of 1, we used it as a host material to fabricate a phosphorescent organic light-emitting diode with an external quantum efficiency of 15 %.

本文言語English
ページ(範囲)23812-23818
ページ数7
ジャーナルAngewandte Chemie - International Edition
60
44
DOI
出版ステータスPublished - 2021 10 25

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

フィンガープリント

「An Air- and Water-Stable B<sub>4</sub>N<sub>4</sub>-Heteropentalene Serving as a Host Material for a Phosphorescent OLED」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル