An Element-Substituted Cyclobutadiene Exhibiting High-Energy Blue Phosphorescence

Yoshiaki Shoji, Yasuhiro Ikabata, Ivan Ryzhii, Rabia Ayub, Ouissam El Bakouri, Taiga Sato, Qi Wang, Tomoaki Miura, Buddhika S.B. Karunathilaka, Youichi Tsuchiya, Chihaya Adachi, Henrik Ottosson, Hiromi Nakai, Tadaaki Ikoma, Takanori Fukushima*

*この研究の対応する著者

研究成果: Article査読

1 被引用数 (Scopus)

抄録

1,3,2,4-Diazadiboretidine, an isoelectronic heteroanalogue of cyclobutadiene, is an interesting chemical species in terms of comparison with the carbon system, whereas its properties have never been investigated experimentally. According to Baird's rule, Hückel antiaromatic cyclobutadiene acquires aromaticity in the lowest triplet state. Here we report experimental and theoretical studies on the ground- and excited-state antiaromaticity/aromaticity as well as the photophysical properties of an isolable 1,3,2,4-diazadiboretidine derivative. The crystal structure of the diazadiboretidine derivative revealed that the B2N2 ring adopts a planar rhombic geometry in the ground state. Yet, theoretical calculations showed that the B2N2 ring turns to a square geometry with a nonaromatic character in the lowest triplet state. Notably, the diazadiboretidine derivative has the lowest singlet and triplet states lying at close energy levels and displays blue phosphorescence.

本文言語English
ページ(範囲)21817-21823
ページ数7
ジャーナルAngewandte Chemie - International Edition
60
40
DOI
出版ステータスPublished - 2021 9 27

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

フィンガープリント

「An Element-Substituted Cyclobutadiene Exhibiting High-Energy Blue Phosphorescence」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル