An enantioselective Baylis-Hillman reaction catalyzed by chiral phosphines under atmospheric pressure

Tadakatsu Hayase, Takanori Shibata, Kenso Soai, Yasuo Wakatsuki

研究成果: Article

105 引用 (Scopus)

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2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl (BINAP) catalyzes the enantioselective Baylis-Hillman reaction between pyrimidine- 5-carbaldehydes and acrylates to provide chiral α-methylene ß-hydroxy esters in up to 44% ee under atmospheric pressure.

元の言語English
ページ(範囲)1271-1272
ページ数2
ジャーナルChemical Communications
発行部数12
出版物ステータスPublished - 1998 6 21
外部発表Yes

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ASJC Scopus subject areas

  • Chemistry(all)

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