Analysis of degradation mechanism of lithium iron phosphate battery

Genki Kaneko, Soichiro Inoue, Koichiro Taniguchi, Toshio Hirota, Yushi Kamiya, Yasuhiro Daisho, Shoichi Inami

研究成果: Conference contribution

5 引用 (Scopus)

抄録

The degradation mechanisms of lithium iron phosphate battery have been analyzed with 150 day calendar capacity loss tests and 3,000 cycle capacity loss tests to identify the operation method to maximize the battery life for electric vehicles. Both test results indicated that capacity loss increased under higher temperature and SOC conditions. And also, large increase of internal resistance on the high temperature and high SOC conditions was confirmed by AC impedance tests. The real cycle capacity loss characteristic was derived by subtracting the capacity decrease due to calendar capacity loss during the cycle test from the overall capacity loss characteristic obtained from the cycle test. As a result, it is found that the real capacity loss contains not only structural disorders of electrode but also degradation factors due to the chemical reactions. Characteristics of degradation were quantified with equations based on the chemical kinetics. With this degradation prediction, an operation method was proposed that is compatible with the long life of batteries and the safety driving of a vehicle. As a result, with optimizing the SOC range used in the operation as follows: 30-10% in the warm seasons, 45-25% in the cold seasons, it was found that batteries can last 4 times longer than it used with high SOC range in every season.

元の言語English
ホスト出版物のタイトル2013 World Electric Vehicle Symposium and Exhibition, EVS 2014
出版者Institute of Electrical and Electronics Engineers Inc.
ISBN(印刷物)9781479938322
DOI
出版物ステータスPublished - 2014 10 1
イベント27th World Electric Vehicle Symposium and Exhibition, EVS 2014 - Barcelona
継続期間: 2013 11 172013 11 20

Other

Other27th World Electric Vehicle Symposium and Exhibition, EVS 2014
Barcelona
期間13/11/1713/11/20

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Phosphates
Lithium
Iron
Degradation
Electric vehicles
Reaction kinetics
Chemical reactions
Temperature
Electrodes

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Automotive Engineering
  • Fuel Technology

これを引用

Kaneko, G., Inoue, S., Taniguchi, K., Hirota, T., Kamiya, Y., Daisho, Y., & Inami, S. (2014). Analysis of degradation mechanism of lithium iron phosphate battery. : 2013 World Electric Vehicle Symposium and Exhibition, EVS 2014 [6914847] Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/EVS.2013.6914847

Analysis of degradation mechanism of lithium iron phosphate battery. / Kaneko, Genki; Inoue, Soichiro; Taniguchi, Koichiro; Hirota, Toshio; Kamiya, Yushi; Daisho, Yasuhiro; Inami, Shoichi.

2013 World Electric Vehicle Symposium and Exhibition, EVS 2014. Institute of Electrical and Electronics Engineers Inc., 2014. 6914847.

研究成果: Conference contribution

Kaneko, G, Inoue, S, Taniguchi, K, Hirota, T, Kamiya, Y, Daisho, Y & Inami, S 2014, Analysis of degradation mechanism of lithium iron phosphate battery. : 2013 World Electric Vehicle Symposium and Exhibition, EVS 2014., 6914847, Institute of Electrical and Electronics Engineers Inc., 27th World Electric Vehicle Symposium and Exhibition, EVS 2014, Barcelona, 13/11/17. https://doi.org/10.1109/EVS.2013.6914847
Kaneko G, Inoue S, Taniguchi K, Hirota T, Kamiya Y, Daisho Y その他. Analysis of degradation mechanism of lithium iron phosphate battery. : 2013 World Electric Vehicle Symposium and Exhibition, EVS 2014. Institute of Electrical and Electronics Engineers Inc. 2014. 6914847 https://doi.org/10.1109/EVS.2013.6914847
Kaneko, Genki ; Inoue, Soichiro ; Taniguchi, Koichiro ; Hirota, Toshio ; Kamiya, Yushi ; Daisho, Yasuhiro ; Inami, Shoichi. / Analysis of degradation mechanism of lithium iron phosphate battery. 2013 World Electric Vehicle Symposium and Exhibition, EVS 2014. Institute of Electrical and Electronics Engineers Inc., 2014.
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