Anchoring effect and oxygen redox property of Co/La0.7Sr0.3AlO3-Δ perovskite catalyst on toluene steam reforming reaction

Kent Takise, Shota Manabe, Keisuke Muraguchi, Takuma Higo, Shuhei Ogo, Yasushi Sekine

研究成果: Article査読

21 被引用数 (Scopus)

抄録

To elucidate specific functions of supports, we investigated steam reforming of toluene as a model compound of biomass tar over Co catalyst supported on perovskite-type oxide. Co-supported La0.7Sr0.3AlO3-δ catalyst showed the highest activity among various Co-supported catalysts. STEM measurements and XPS measurements revealed the coexistence of La cation and lattice oxygen defect produces an anchoring effect to Co particles. The lattice oxygen release rate on each catalyst was measured with H218O steady-state isotopic transient kinetic analysis (SSITKA). The anchoring effect, higher dispersion of Co and redox property, are important for the high catalytic performance of Co/La0.7Sr0.3AlO3-δ catalyst on toluene steam reforming.

本文言語English
ページ(範囲)181-189
ページ数9
ジャーナルApplied Catalysis A: General
538
DOI
出版ステータスPublished - 2017

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

フィンガープリント 「Anchoring effect and oxygen redox property of Co/La<sub>0.7</sub>Sr<sub>0.3</sub>AlO<sub>3-Δ</sub> perovskite catalyst on toluene steam reforming reaction」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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