Anion conductive aromatic polymers containing fluorenyl groups: Effect of the position and number of ammonium groups

Manai Shimada, Shigefumi Shimada, Junpei Miyake, Makoto Uchida, Kenji Miyatake

研究成果: Article査読

22 被引用数 (Scopus)

抄録

Synthesis and properties of anion conductive aromatic block copolymers, QPE-bl-3, QPE-bl-3 M2, and M4, containing fluorenylidene biphenylene groups as scaffold for ammonium groups are described. These copolymers share the same main chain structure, but the position and the number of ammonium groups on a fluorenyl group differ. High molecular weight quaternized block copolymers were obtained via typical chloromethylation reaction or using preaminated monomers, and were well-characterized by 1H NMR spectra. Self-standing bendable membranes were obtained by solution casting. QPE-bl-3 M4 membranes containing four ammonium groups per hydrophilic repeat unit (highest ammonium density) in the hydrophilic block exhibited well developed phase-separated morphology, while QPE-bl-3 membranes containing two ammonium groups per hydrophilic repeat unit exhibited high anion conductivity. The highest anion conductivity (104 mS/cm) was obtained with QPE-bl-3 membrane (IEC = 2.1 meq/g) at 80 C in water. An H2/O2 alkaline fuel cell was operable with the membrane to achieve 62 mW/cm2 of the maximum power density at 161 mA/cm2 of the current density.

本文言語English
ページ(範囲)935-944
ページ数10
ジャーナルJournal of Polymer Science, Part A: Polymer Chemistry
54
7
DOI
出版ステータスPublished - 2016 4 1
外部発表はい

ASJC Scopus subject areas

  • ポリマーおよびプラスチック
  • 有機化学
  • 材料化学

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