Anomalous Potential Shifts of Redox-active Molecules in Highly Concentrated Electrolytes

Kan Hatakeyama-Sato*, Satoshi Matsumoto, Ikuma Aida, Kenichi Oyaizu

*この研究の対応する著者

研究成果: Article査読

抄録

Redox potentials of various redox-active molecules were examined in highly concentrated electrolytes. At the high concentration regions, the shifts were significantly larger than the conventional trend («0.059 V/dec) expected from the salt concentration terms in the Nernst equation. Decreased activity of the molecular salts was considered to explain the shift. The dramatic potential changes will play essential roles in designing molecule-based energy devices.

本文言語English
ページ(範囲)1375-1377
ページ数3
ジャーナルChemistry Letters
50
7
DOI
出版ステータスPublished - 2021 7

ASJC Scopus subject areas

  • 化学 (全般)

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