Aromatic C-H coupling with hindered arylboronic acids by Pd/Fe dual catalysts

Kazuya Yamaguchi, Hiroki Kondo, Junichiro Yamaguchi, Kenichiro Itami

研究成果: Article

82 被引用数 (Scopus)

抄録

An aerobic oxidative coupling of arenes/alkenes with arylboronic acids (C-H/C-B coupling) using catalytic Pd(II)-sulfoxide-oxazoline (sox) ligand and iron-phthalocyanine (FePc) has been developed. This dual catalyst system enables the synthesis of sterically hindered heterobiaryls and styrene derivatives under air without stoichiometric co-oxidants. Additionally, this chemistry demonstrated an advance toward an enantioselective biaryl coupling through C-H functionalization.

元の言語English
ページ(範囲)3753-3757
ページ数5
ジャーナルChemical Science
4
発行部数9
DOI
出版物ステータスPublished - 2013 7 29

ASJC Scopus subject areas

  • Chemistry(all)

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