Asymmetric vinylogous Mukaiyama aldol reactions using vinylketene N,O-acetals in total syntheses of natural products

Seijiro Hosokawa, Kuniaki Tatsuta

    研究成果: Article

    52 引用 (Scopus)

    抄録

    Asymmetric vinylogous aldol reaction is a powerful methodology to introduce a multi functional group in the stereoselective manner. Recently, we have developed highly stereoselective vinylogous Mukaiyama aldol reactions using vinylketene N,O-acetals possessing the chiral oxazolidone. Our methodology has been applied to the asymmetric syntheses of natural products to establish the short and efficient routes. This review focuses on the asymmetric vinylogous Mukaiyama aldol reactions using vinylketene N,O-acetals in total syntheses of natural products.

    元の言語English
    ページ(範囲)1-18
    ページ数18
    ジャーナルMini-Reviews in Organic Chemistry
    5
    発行部数1
    DOI
    出版物ステータスPublished - 2008 2

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    Acetals
    Biological Products
    Functional groups
    3-hydroxybutanal

    ASJC Scopus subject areas

    • Organic Chemistry

    これを引用

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