Asymmetric vinylogous Mukaiyama aldol reactions using vinylketene N,O-acetals in total syntheses of natural products

Seijiro Hosokawa, Kuniaki Tatsuta

研究成果: Review article査読

54 被引用数 (Scopus)

抄録

Asymmetric vinylogous aldol reaction is a powerful methodology to introduce a multi functional group in the stereoselective manner. Recently, we have developed highly stereoselective vinylogous Mukaiyama aldol reactions using vinylketene N,O-acetals possessing the chiral oxazolidone. Our methodology has been applied to the asymmetric syntheses of natural products to establish the short and efficient routes. This review focuses on the asymmetric vinylogous Mukaiyama aldol reactions using vinylketene N,O-acetals in total syntheses of natural products.

本文言語English
ページ(範囲)1-18
ページ数18
ジャーナルMini-Reviews in Organic Chemistry
5
1
DOI
出版ステータスPublished - 2008 2 1

ASJC Scopus subject areas

  • 有機化学

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