Atomic origins of the high catalytic activity of nanoporous gold

Takeshi Fujita*, Pengfei Guan, Keith McKenna, Xingyou Lang, Akihiko Hirata, Ling Zhang, Tomoharu Tokunaga, Shigeo Arai, Yuta Yamamoto, Nobuo Tanaka, Yoshifumi Ishikawa, Naoki Asao, Yoshinori Yamamoto, Jonah Erlebacher, Mingwei Chen

*この研究の対応する著者

研究成果: Article査読

733 被引用数 (Scopus)

抄録

Distinct from inert bulk gold, nanoparticulate gold has been found to possess remarkable catalytic activity towards oxidation reactions. The catalytic performance of nanoparticulate gold strongly depends on size and support, and catalytic activity usually cannot be observed at characteristic sizes larger than 5ĝ‰nm. Interestingly, significant catalytic activity can be retained in dealloyed nanoporous gold (NPG) even when its feature lengths are larger than 30-nm. Here we report atomic insights of the NPG catalysis, characterized by spherical-aberration-corrected transmission electron microscopy (TEM) and environmental TEM. A high density of atomic steps and kinks is observed on the curved surfaces of NPG, comparable to 3-5nm nanoparticles, which are stabilized by hyperboloid-like gold ligaments. In situ TEM observations provide compelling evidence that the surface defects are active sites for the catalytic oxidation of CO and residual Ag stabilizes the atomic steps by suppressing {111} faceting kinetics.

本文言語English
ページ(範囲)775-780
ページ数6
ジャーナルNature Materials
11
9
DOI
出版ステータスPublished - 2012 9月
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学
  • 材料力学
  • 機械工学

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