Band-like temperature dependence of mobility in a solution-processed organic semiconductor

Tomo Sakanoue*, Henning Sirringhaus

*この研究の対応する著者

研究成果: Article査読

352 被引用数 (Scopus)

抄録

The mobility μ of solution-processed organic semiconductorshas improved markedly to room-temperature values of 1-5 cm 2 V -1 s -1. In spite of their growing technological importance, the fundamental open question remains whether charges are localized onto individual molecules or exhibit extended-state band conduction like those in inorganic semiconductors. The high bulk mobility of 100 cm 2 V -1 s -1 at 10 K of some molecular single crystals provides clear evidence that extended-state conduction is possible in van-der-Waals-bonded solids at low temperatures. However, the nature of conduction at room temperature with mobilities close to the Ioffe-Regel limit remains controversial. Here we investigate the origin of an apparent band-like, negative temperature coefficient of the mobility (dμ/dT<0) in spin-coated films of 6,13-bis(triisopropylsilylethynyl)-pentacene. We use optical spectroscopy of gate-induced charge carriers to show that, at low temperature and small lateral electric field, charges become localized onto individual molecules in shallow trap states, but that a moderate lateral electric field is able to detrap them resulting in highly nonlinear, low-temperature transport. The negative temperature coefficient of the mobility at high fields is not due to extended-state conduction but to localized transport limited by thermal lattice fluctuations.

本文言語English
ページ(範囲)736-740
ページ数5
ジャーナルNature Materials
9
9
DOI
出版ステータスPublished - 2010 9月
外部発表はい

ASJC Scopus subject areas

  • 機械工学
  • 材料力学
  • 凝縮系物理学
  • 材料科学(全般)
  • 化学 (全般)

フィンガープリント

「Band-like temperature dependence of mobility in a solution-processed organic semiconductor」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル